化学学报 ›› 1994, Vol. 52 ›› Issue (7): 639-645. 上一篇    下一篇

研究论文

热动力学对比进度法IV. 热导式热量计的单参数理论模型与热谱重建

刘劲松;曾宪诚;邓郁;田安民   

  1. 四川大学化学系
  • 发布日期:1994-07-15

Reduced extent method for thermokinetics IV. a single-parameter theoretical model of a conduction calorimeter and thermogram reconstruction

LIU JINSONG;ZENG XIANCHENG;DENG YU;TIAN ANMIN   

  • Published:1994-07-15

本文建立了热导式热量计的单参数理论模型, 在此基础上系统地提出了热谱重建法, 并结合热动力学对比进度法, 对几个化学反应体系进行了热动力学研究。实验结果验证了本文方法及其理论基础的正确性。

关键词: 量热法, 热谱, 热动力学, 对比进度法, 参数理论模型, 热量式量热计

A single-parameter theor. model of a conduction calorimeter has been suggested. On the basis of the model a thermogram reconstruction method was proposed. This method, combining with reduced extent method, was applied to the studies of thermokinetics of some chem. reacting systems. The reliability of this method and its theor. basis have been verified by the experimental results.p

Key words: CALORIMETRY, THERMOGRAPHY, THERMODYNAMICS

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