化学学报 ›› 1991, Vol. 49 ›› Issue (7): 665-670. 上一篇    下一篇

研究论文

d^3的C2v电子能级和CoCl4^2电子光谱解析

豆育升;文振翼;张棣   

  1. 西北大学化学系;西北大学现代物理研究所
  • 发布日期:1991-07-15

The electron energy levels of d^3 configurations in C2v symmetry field and analysis of electronic spectra of CoCl4^2 ion

DOU YUSHENG;WEN ZHENYI;ZHANG DI   

  • Published:1991-07-15

本文计算了d^3电子组态在C2v场中的全部能量矩阵元, 微扰算符包括静电算符、晶场算符和旋轨偶合算符, 讨论了拟合了Cs2CoCl4的电子光谱。

关键词: 碳原子, 电子组态, 微扰论, 电子光谱学, 配位场理论, 氯化钴, 能量矩阵, 铯络合物

The energy matrixes were calculated for the d3 configurations in C2v symmetry field by use of the unitary group approach. The perturbation Hamiltonian consists of Coulomb, crystal and spin-orbit coupling operators. On basis of these energy matrixes, electronic spectra of CoCl42- ion were assigned.

Key words: CARBON ATOM, ELECTRON CONFIGURATION, PERTURBATION THEORY, ELECTRON SPECTROSCOPY, LIGAND FIELD THEORY, COBALT CHLORIDE, ENERGY MATRIX, CESIUM COMPLEX

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