化学学报 ›› 1991, Vol. 49 ›› Issue (5): 488-492. 上一篇    下一篇

研究论文

线性变位极谱法研究 XIV: 配位吸附准可逆波电化学参数的测定

丁世家;张祖训   

  1. 南京大学化学系
  • 发布日期:1991-05-15

Investigation on polarography with changing potential XIV: Determination of electrochemical parameters for the adsorptive-complex quasi-reversible wave

DING SHIJIA;ZHANG ZUXUN   

  • Published:1991-05-15

本文讨论配位吸附准可逆波测定标准电极反应速率常数(kα)和转移系数(α)的理论与方法, 实验结果证实, 方法简便, 结果正确。

关键词: 示波极谱法, 络合物, 铅, 铜离子, 极谱分析, 参数, 反应速度常数, 电化学分析, 铟离子, 羟基喹啉类

The theory on the determination of standard rate constant of electrochem. reaction (ks) and transfer coefficient (a) is presented for the adsorptive-complex quasi-reversible wave. Experimental results show that the methods are simple and reliable. Pb(II)-8-oxine, Cu(II)-8-oxine, and In(III)-PAR systems were studied.

Key words: OSCILLOSCOPIC POLAROGRAPHY, COMPLEX COMPOUNDS, LEAD, COPPER ION, POLAROGRAPHIC ANALYSIS, PARAMETER, REACTION RATE CONSTANT, ELECTROCHEMICAL ANALYSIS, INDIUM ION, HYDROXY QUINOLINES

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