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化学学报
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化学学报 ›› 1990, Vol. 48 ›› Issue (5): 511-515. 上一篇    下一篇

研究论文

具有生物活性的有机硅化合物的研究IX:1-(N-芳基呋喃甲酰胺)亚甲基-2,8,9-三氧杂-5-氮杂-1-硅杂三环[3.3.3.O^1^.^5]十一烷的合成

廖仁安;谢庆兰;吴益民   

  1. 南开大学元素有机化学研究所
  • 发布日期:1990-05-15

Studies on organo-silicon compounds with biological activity IX: synthesis of 1-(N-arylfuroylamidomethyl)-2,8,9-trioxa-5-aza-1-silatricyclo[3.3.3O^1^.^5] undecanes

LIAO RENAN;XIE QINGLAN;WU YIMIN   

  • Published:1990-05-15

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本文合成了六个1-(N-芳基呋喃甲酰胺)亚甲基-2,8,9-三氧杂-5-氮杂-1-硅杂三环[3.3.3.O^1^.^5]十一烷的化合物。合成方法简便, 反应时间短。易于后处理。经元素分析, IR, ^1H NMR, MS确定了新化合物的结构, 并经化合物3的X射线晶格衍射分析确定了该类化合物的空间排布情况。

关键词: 生物活性, 红外分光光度法, 元素分析, 质谱法, 氮杂环化合物, 质子磁共振谱法, 氧杂环化合物, 有机硅化合物, 十一碳化合物, 硅杂环化合物

Six 1-(N-arylsulfoylamidomethyl)-2,8,9-trioxa-5-aza-1-silatricyclo[3.3.3.01,5] undecanes I (R = Ph, 2-, 4-MeC6H4, 2-MeOC6H4, 2-ClC6H4, 2-BrC6H4) were synthesized. Their structures were established by elemental anal., IR, 1H NMR, and mass spectra. The crystal structure of I (R = 2-MeC6H4) was determine

Key words: BIOLOGICAL ACTIVITY, INFRARED SPECTROPHOTOMETRY, ELEMENTAL ANALYSIS, MASS SPECTROGRAPHY, NITROGEN HETEROCYCLICS, PROTON MAGNETIC RESONANCE SPECTROMETRY, OXYGEN HETEROCYCLICS, ORGANO SILICON COMPOUNDS, C11 COMPOUNDS, SILICON HETEROCYCLICS COMPOUNDS

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