化学学报 ›› 1990, Vol. 48 ›› Issue (4): 343-348. 上一篇    下一篇

研究论文

碎片法合成金属原子簇:Isolobal Analogy的应用和推广

黄锦顺;王银桂;张乾二;卢嘉锡   

  1. 中国科学院福建物质结构研究所
  • 发布日期:1990-04-15

Research on the synthesis of metal clusters from reactive fragements: The applications and extensions of the isolobal analogy

HUANG JINSHUN;WANG YINGUI;ZHANG QIANER;LU JIAXI   

  • Published:1990-04-15

本文讨论了等瓣相似原理的推广并应用于混合金属原子簇化合物的合成。特别是把等瓣相似概念作进一步地推广, 即满足于9n-l规则的金属簇合物等瓣相似于满足4n-1规则的碳烷, 因此等瓣相似概念以及它的推广在碎片法合成金属簇合物的研究中是十分有用的。

关键词: 簇状化合物, 结构化学, 碎片, 等瓣相似, 元素有机化学

A review with 11 refs. on the extended isolobal analogy and its application in the synthesis of mixed metal clusters. The isolobal analogy could serve as a guide in synthesis of new metal cluster compounds from reactive fragments.p

Key words: CLUSTER COMPOUND, STRUCTURAL CHEMISTRY, FRAGMENTS, ISOLOBAL ANALOGY, ELEMENTARY ORGANIC CHEMISTRY

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