化学学报 ›› 2005, Vol. 63 ›› Issue (7): 587-591. 上一篇    下一篇

研究论文

聚电解质膜PDAC/PSS诱导CaCO3结晶的研究

杜竹玮*,郝娟玲,李浩然   

  1. (中国科学院过程工程研究所 生化工程国家重点实验室 北京 100080)
  • 投稿日期:2004-07-09 修回日期:2004-12-07 发布日期:2010-12-10
  • 通讯作者: 杜竹玮

Control of CaCO3 Crystal Growth on PDAC/PSS Self-Assembled Multilayers

DU Zhu-Wei*, HAO Juan-Ling, LI Hao-Ran   

  1. (National Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100080)
  • Received:2004-07-09 Revised:2004-12-07 Published:2010-12-10

以模拟软体动物珍珠层的周期性基质控制形成过程制备仿生层状复合材料. 将聚苯乙烯磺酸钠(PSS)与聚二烯二甲基氯化铵(PDAC)用逐层浸渍的方法使其组装成多层膜, 用于诱导过饱和溶液中CaCO3的结晶, 详细研究了膜紫外吸收随组装层数增加的线性变化. 扫描电镜和X射线衍射表征了晶体的形貌和结构. (PDAC/PSS)15PDAC膜诱导获得的CaCO3晶体为六面体结构, 晶体尺寸为30~40 μm; (PDAC/PSS)15膜诱导CaCO3结晶, 可以在膜表面获得形貌与珍珠层非常相似的CaCO3晶体, 结晶10 h获得的晶片结构呈规则的六边形, 片尺寸约为10~20 μm. X射线衍射结果表明两种晶体的晶格结构与天然珍珠层差异明显, 说明静电作用为晶体形貌的主控因素之一, 但不是晶格结构的决定因素. 复合材料断面电镜照片表明其为层状结构.

关键词: 自组装膜, 碳酸钙, 仿生矿化, 珍珠层

Fabrication of biomimetic laminated composite by mimicking the cyclical matrix control process to form the highly structured Mollusca nacre was presented in this paper. (PDAC/PSS)n self-assembled multilayers were built-up through alternative adsorption of polycation and polyanion to a substrate as matrices and their chemical structure was characterized by UV-vis absorption spectra. And then the deposition of CaCO3 took place on the multilayers by dipping them into a supersaturated CaCO3 solution. The crystals regulated by (PDAC/PSS)15PDAC exhibited hexahedral shape and had a size of about 30~40 μm after 10 h deposition. Hexagonal CaCO3 platelet crystals could be observed on (PDAC/PSS)15 with a relative small size of 10~20 μm, which is very similar to the crystals existing in natural nacre. Therefore, CaCO3 crystals with remarkable morphology similarity to natural biomineralization products were obtained in the presence of artificial polyanion. However, X-ray diffraction results indicated that crystal lattice of both the samples was different from any kind of natural nacre. Consequently, it might be supposed that electrostatic effect is one of the key factors in morphology control while the crystal lattice was determined by other factors. Furthermore, end surface SEM image of (PDAC/PSS)15-CaCO3 composite elucidated that alternation of multilayer growth and deposition of inorganic crystals coupled with morphology regulation could form laminated material.

Key words: self-assembled multilayers, calcium carbonate, biomimetic biomineralization, nacre