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化学学报
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化学学报 ›› 2006, Vol. 64 ›› Issue (16): 1615-1621.    下一篇

研究论文

K-MnO/γ-Al2O3和Cu/SiO2催化剂应用于苯甲酸甲酯连续加氢合成无氯苯甲醇

徐华龙, 黄静静, 杨新艳, 杜俊明, 沈江, 沈伟*   

  1. (复旦大学化学系 上海市分子催化与功能材料重点实验室 上海 200433)
  • 投稿日期:2006-01-11 修回日期:2006-03-13 发布日期:2006-08-28
  • 通讯作者: 沈伟

Consecutive Hydrogenation of Methyl Benzoate to Non-Chloride Benzyl Alcohol over K-MnO/γ-Al2O3 and Cu/SiO2 Catalysts

XU Hua-Long; HUANG Jing-Jing; YANG Xin-Yan; DU Jun-Ming; SHEN Jiang; SHEN Wei*   

  • Received:2006-01-11 Revised:2006-03-13 Published:2006-08-28
  • Contact: SHEN Wei

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以K-MnO/γ-Al2O3和Cu/SiO2为催化剂, 利用固定床串联反应器实现了苯甲酸甲酯连续加氢合成无氯苯甲醇反应过程. K-MnO/γ-Al2O3和Cu/SiO2催化剂对于苯甲酸甲酯连续加氢合成苯甲醇具有良好的加氢活性, 反应转化率可达89.2%, 苯甲醇的选择性为84.1%. 在苯甲酸甲酯加氢连续步骤中的氢醛比得到提高, 有效地抑制了副产物甲苯的生成. XRD, SEM和TPR表征结果表明: 采用吸附沉淀法制备的Cu/SiO2-C15.2催化剂, 氧化铜在载体上具有良好的分散性能, 并且易于还原, 表现出最佳的苯甲醛加氢活性.

关键词: 连续催化加氢, 苯甲醇, 苯甲酸甲酯, K-MnO/g-Al2O3, Cu/SiO2 催化剂

Consecutive hydrogenation of methyl benzoate to non-chloride benzyl alcohol over K-MnO/ γ-Al2O3 and Cu/SiO2 catalysts was investigated in a fixed-bed stainless-steel reactor. The effects of reaction conditions on catalytic activity were also studied. The results indicated that Cu/SiO2 prepared by adsorbed- precipitation method owned larger pore diameter and volume than others, CuO dispersed well on the surface of catalyst, and it was easily re-duced at relative lower temperature. K-MnO/γ-Al2O3 and Cu/SiO2-C15.2 exhibited higher activity and selectivity for continuous hydrogenation of methyl benzoate to benzyl alcohol, the conversion of methyl benzoate was 89.2% and the selectivity of ben-zyl alcohol reached 84.1%. Molar ratio of hydrogen to benzaldehyde was increased in consecutive hydro-genation process, which is beneficial to enhancing the selectivity of benzyl alcohol. Characterization results of XRD, SEM and TPR revealed that CuO dispersed well on Cu/SiO2-C catalyst which pre-pared by adsorption-precipitation method, and it showed best activity for hydrogenation of benzaldehyde to benzyl alcohol.

Key words: continuous hydrogenation, benzyl alcohol, methyl benzoate, K-MnO/γ-Al2O3, Cu/SiO2 catalyst