长链阳离子表面活性剂蠕虫状胶束的剪切带转变行为研究

doi:10.6023/A1202012

化学学报 ›› 2012, Vol. 70 ›› Issue (14): 1551-1554.DOI: 10.6023/A1202012 上一篇下一篇

研究论文

长链阳离子表面活性剂蠕虫状胶束的剪切带转变行为研究

楚宗霖^a,b,c, 张永民^b,c, 韩玉贵^a, 王红艳^a,b, 李彬^a,b, 冯玉军^a,b

a 中国石化胜利油田地质科学研究院采收率室东营 257015;
b 中国科学院成都有机化学研究所成都 610041;
c 中国科学院研究生院北京 100049

投稿日期:2012-02-01 发布日期:2012-05-16
通讯作者: 冯玉军
基金资助:
项目受山东省“泰山学者”岗位建设;国家自然科学基金(No. 21173207);四川省杰出青年科学基金(No. 2010JQ0029);四川省科技支撑计划(No. 2012NZ0006)资助.

Shear Banding Transition of Wormlike Micelles Formed by a C₂₂-Tailed Cationic Surfactant

Chu Zonglin^a,b,c, Zhang Yongmin^b,c, Han Yugui^a, Wang Hongyan^a,b, Li Bin^a,b, Feng Yujun^a,b

a EOR Laboratory of Geological Scientific Research Institute, Shengli Oilfield Company of SINOPEC, Dongying 257015;
b Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041;
c Graduate University of the Chinese Academy of Sciences, Beijing 100049

Received:2012-02-01 Published:2012-05-16
Supported by:
Project supported by the Shandong Provincial Government through its ‘‘Taishan Scholar’’ project, the Natural Science Foundation of China (No. 21173207), and Science and Technology Department of Sichuan Province through its “Sichuan Distinguished Youth Fund” (No. 2010JQ0029) and “Sichuan Pillar Program from Science and Technology” (No. 2012NZ0006).

文章分享

摘要/Abstract

报道一种含有不饱和疏水尾链的超长链阳离子表面活性剂——N-芥酸酰胺丙基-N,N,N-三甲基碘化铵(EDAI)自组装所形成的蠕虫状胶束及其剪切带行为. EDAI浓溶液表现出了明显的剪切带转变特征, 即溶液的流动曲线被介于两个临界剪切速率之间的剪切应力平台分割为粘度不同的两部分. 在剪切带转变区域, 原本均质的流体表现出机械剪切不稳定性, 沿速度梯度方向被分割为剪切速率不同的两个宏观流体层.

关键词: 长链表面活性剂, 蠕虫状胶束, 剪切带, 流变学性能, 粘弹性

Both fundamental and technological research interests highlighted in the past few decades on surfactant self-assembly wormlike micellar aggregates. We report herein the shear-banding transition of wormlike micelles formed by a novel C₂₂-tailed cationic surfactant, N-erucylamidopropyl-N,N,N-trimethylammonium iodide (EDAI) in aqueous solution. Steady and dynamic rheological measurements indicate that concentrated EDAI solution is strongly viscoelastic, which can be attributed to the presence of wormlike micelles in the solution. Rheological tests implies that the concentrated EDAI worm solution shows typical characteristic of shear banding transition, i.e., the flow curve is composed of two branches corresponding to high and low viscosities separated by a stress plateau between two critical shear rates. In the shear banding transition region, the fluid is mechanically unstable and the initial homogeneous flow was spurted into two macroscopic layers bearing different shear rates and stacked along the velocity gradient direction. The shear-banding transition behavior was further directly observed on a visualization rheometer.

Key words: long-chain surfactant, wormlike micelles, shear banding, rheological properties, viscoelasticity

引用此文

楚宗霖, 张永民, 韩玉贵, 王红艳, 李彬, 冯玉军. 长链阳离子表面活性剂蠕虫状胶束的剪切带转变行为研究[J]. 化学学报, 2012, 70(14): 1551-1554.

Chu Zonglin, Zhang Yongmin, Han Yugui, Wang Hongyan, Li Bin, Feng Yujun. Shear Banding Transition of Wormlike Micelles Formed by a C₂₂-Tailed Cationic Surfactant[J]. Acta Chimica Sinica, 2012, 70(14): 1551-1554.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

参考文献

[1] Hoffmann, H. Adv. Mater. 1994, 6, 116.
[2] Dreiss, C. A. Soft Matter 2007, 3, 956.
[3] Cates, M. E. Macromolecules 1987, 20, 2289.
[4] Cates, M. E.; Candau, S. J. J. Phys.: Condens. Matter 1990, 2, 6869.
[5] Rehage, H.; Hoffmann, H. Mol. Phys. 1991, 74, 933.
[6] Yang, J. Curr. Opin. Colloid Interface Sci. 2002, 7, 276.
[7] Stukan, M. R.; Boek, E. S.; Padding, J. T.; Briels, W. J.; Crawshaw, J. P. Soft Matter 2008, 4, 870.
[8] Qi, Y.; Zakin, J. L. Ind. Chem. Res. 2002, 41, 6326.
[9] Kefi, S.; Lee, J.; Pope, T. L.; Sullivan, P.; Nelson, E.; Hernandez, A. N.; Olsen, T.; Parlar, M.; Powers, B.; Roy, A.; Wilson, A.; Twynam, A. Oilfield Rev. 2004, 16, 10.
[10] Li, X. P.; Yu, L.; Ji, Y. Q.; Wu, B.; Li, G. Z.; Zheng, L. Q. Chin. Chem. Lett. 2009, 20, 1251.
[11] Chu, Z.; Feng, Y.; Sun, H.; Li, Z.; Song, X.; Han, Y.; Wang, H. Soft Matter 2011, 7, 4485.
[12] Spenley, N. A.; Cates, M. E.; McLeish, T. C. B. Phys. Rev. Lett. 1993, 71, 939.
[13] Callaghan, P. T.; Cates, M. E.; Rofe, C. J.; Smeulders, J. B. A. F. J. Phys. II 1996, 6, 375.
[14] Grand, C.; Arrault, J.; Cates, M. E. J. Phys. II 1997, 7, 1071.
[15] Hassan, P. A.; Valaulikar, B. S.; Manohar, C.; Kern, F.; Bourdieu, L.; Candau, S. J. Langmuir 1996, 12, 4350.
[16] Buhler, E.; Candau, S. J.; Kolomiets, E.; Lehn, J. M. Phys Rev. E 2007, 76, 061804.
[17] Berret, J.-F.; Roux, D. C.; Porte, G. J. Phys. II 1994, 4, 1261.
[18] Berret, J.-F. In Molecular Gels: Materials with Self-Assembled Fibrillar Networks, Eds.: Weiss, R. G.; Terech, P., Springer, Dordrecht, the Netherlands, 2006.
[19] Lerouge, S.; Berret, J.-F. Adv. Polym. Sci. 2010, 230, 1.
[20] Chu, Z.; Feng, Y.; Su, X.; Han, Y. Langmuir 2010, 26, 7783.
[21] Chu, Z.; Feng, Y. Soft Matter 2010, 6, 6065.
[22] Kumar, R.; Kalur, G. C.; Ziserman, L.; Danino, D.; Raghavan, S. R. Langmuir 2007, 23, 12849.
[23] Feng, D.; Zhang, Y.; Chen, Q.; Wang, J.; Li, B.; Feng, Y. J. Surfactants Deterg. 2012, DOI: 10.1007/s11743-012-1359-7.
[24] Corce, V.; Cosgrove, T.; Maitland, G.; Hughes, T.; Karlsson, G. Langmuir 2003, 19, 8536.
[25] Raghavan, S. R.; Edlund, H.; Kaler, E. W. Langmuir 2002, 18, 1056.
[26] Han, Y.; Feng, Y.; Sun, H.; Li, Z.; Han, Y.; Wang, H. J. Phys. Chem. B 2011, 115, 6893.
[27] Chu, Z.; Feng, Y. Synlett 2009, 20, 2655.
[28] Chu, Z.; Feng, Y. Langmuir 2012, 28, 1175.
[29] Croce, V.; Cosgrove, T.; Dreiss, C. A.; King, S.; Maitland, G.; Hughes, T. Langmuir 2005, 21, 6762.
[30] Rehage, H.; Hoffmann, H. Mol. Phys. 1991, 74, 933.
[31] Decruppe, J. P.; Cressely, R.; Makhloufi, R.; Cappelaere, E. Colloid Polym. Sci. 1995, 273, 346.
[32] Lerouge, S.; Fardin, M. A.; Argentina, M.; Gr閛rie, G.; Cardoso, O. Soft Matter 2008, 4, 1808.
[33] Raudsepp, A.; Callaghan, P. T. Soft Matter 2008, 4, 784.

长链阳离子表面活性剂蠕虫状胶束的剪切带转变行为研究

Shear Banding Transition of Wormlike Micelles Formed by a C₂₂-Tailed Cationic Surfactant

PDF

可视化

被引次数

摘要/Abstract

引用此文

分享此文

参考文献

相关文章 10

编辑推荐

相关统计

本文评价

[1]	张娜, 陈国君, 陈坤, 李洪光, 郝京诚. 无盐阴/阳离子表面活性剂稳定的粘弹性乳液[J]. 化学学报, 2015, 73(8): 835-839.
[2]	范海明, 吴晓燕, 黄经纬, 徐海, 刘述忍, 王永健, 李渊, 康万利. 两性/阴离子表面活性剂形成具有耐盐性能的蠕虫状胶束[J]. 化学学报, 2011, 69(17): 1997-2002.
[3]	张旭锋, 吴文辉. 阴离子疏水缔合共聚物/阳离子蠕虫状胶束协同增粘自组装网络[J]. 化学学报, 2009, 67(20): 2381-2384.
[4]	胡志标, 王永强, 曾广鹏, 张超, 夏必来, 洪昕林, 张高勇. 催化链转移聚合制备接枝型两亲共聚物及其溶液性质研究[J]. 化学学报, 2007, 65(23): 2656-2662.
[5]	曹泉,于丽,孙立新, 郑利强, 李干佐. 由碳酸钠诱导形成的油酸钠蠕虫状胶束的流变学性质[J]. 化学学报, 2007, 65(17): 1821-1825.
[6]	王志宁, 郑利强, 李干佐. 蔗糖对MO/水立方液晶体系流变性质的影响[J]. 化学学报, 2005, 63(4): 274-278.
[7]	唐晓林,张林霞,王涛,李善君. 聚醚砜改性环氧树脂体系粘弹性相分离的研究[J]. 化学学报, 2005, 63(4): 321-326.
[8]	李传宪,张春光,孙德罕,李琦瑰. 原油溶胶-凝胶等温转变过程中的流变性研究[J]. 化学学报, 2003, 61(3): 363-366.
[9]	牟建海,李干佐,陈文君,毛宏志,刘少杰. 十二烷基聚氧乙烯硫酸钠胶束体系的流变性质研究[J]. 化学学报, 2001, 59(9): 1384-1388.
[10]	王红霞,张高勇. 非离子表面活性剂液晶的线性粘弹性研究[J]. 化学学报, 2001, 59(11): 1888-1893.

长链阳离子表面活性剂蠕虫状胶束的剪切带转变行为研究

Shear Banding Transition of Wormlike Micelles Formed by a C22-Tailed Cationic Surfactant

PDF

可视化

被引次数

摘要/Abstract

引用此文

分享此文

参考文献

相关文章 10

编辑推荐

相关统计

本文评价

Shear Banding Transition of Wormlike Micelles Formed by a C₂₂-Tailed Cationic Surfactant