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化学学报
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化学学报 ›› 1982, Vol. 40 ›› Issue (9): 821-827. 上一篇    下一篇

论文

全氟和多氟烷基磺酸的研究——Ⅴ.氟烷基磺酸酯在含氟叔胺合成中的应用

黄维垣, 杜学梅, 何钰清, 黄辉裳, 曹玟娟, 骆昌平   

  1. 中国科学院上海有机化学研究所
  • 投稿日期:1981-03-09 发布日期:2013-06-03
  • 通讯作者: 杜学梅

PERFLUORO AND POLYFLUORO SULFONIC ACIDS Ⅴ. THE APPLICATION OF POLYFLUOROALKYL POLYFLUOROSULFONATE IN THE SYNTHESIS OF FLUORINATED TERTIARY AMINES

HUANG WEI-YUAN, DU XUE-MEI, HE YU-QING, HUANG HUI-SHANG, CAO WEN-JUAN, Luo CHANG-PING   

  1. Shanghai Institute of Organic Chemistry, Academia Sinica
  • Received:1981-03-09 Published:2013-06-03

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776

被引次数

2

本文合成了一系列含氟和全氟磺酸酯1～6。发现它们的反应活性受远离磺酸基的部分分子结构的影响。利用这些磺酸酯合成了含氟叔胺7～10。

A series of new perfluorosnlfonates RO (CF2)2SO3CH2(CF2)4H[R: CH3(1),H (CF2)2H2(2),I (CF2) 2(3),CCl3(4),H (CF2) 4CH2(5),Cl2CFCF2 (6)] are synthesized using aqueous KOH solution or triethylamine as acid absorbent.It is found that the reactivity of these sulfonates is not only influenced by the structure of the group directly connected to the snlfonyl group,but also by that of the part of molecular structure far away therefrom.