化学学报 ›› 1982, Vol. 40 ›› Issue (6): 489-498. 上一篇    下一篇

论文

Cr3+的水解聚合作用 Ⅱ.低浓度下Cr3+的水解聚合作用的研究

罗勤慧, 沈孟长, 丁益, 戴安邦   

  1. 南京大学配位化学研究所
  • 投稿日期:1981-03-30 发布日期:2013-06-03
  • 通讯作者: 罗勤慧

STUDIES ON HYDROLYTIC POLYMERIZATION OF CHROMIUM (Ⅲ) ION Ⅱ. A STUDY ON HYDROLYTIC POLYMERIZATION OF Cr3+ AT LOW CONCENTRATION

LUO QING-HUI, SHEN MENG-CHANG, DING YI, DAI AN-BANG(TAI AN-PANG)   

  1. Coordination Chemistry Research Institute, Nanjing University
  • Received:1981-03-30 Published:2013-06-03

本文研究了Cr3+在0.0025~0.0002M浓度范围内的水解聚合作用.用平均组成法求得了各种水解产物的组成,表明各种产物以三核络阳离子占优势.但随着Cr3+浓度的降低和pH值的升高,与Cr3+结合的OH-数增加.用作图外推法计算了水解常数.在不同的pH范围,同一产物的水解常数能很好地吻合,且其中的β43与Ⅰ报中所得结果基本一致.本文所求得的组成与过去用聚沉值法所得的多核配离子电荷数基本符合.

The hydrolytic polymerization of chromium (Ⅲ) ion was investigated in the concentration rango of 0.0025M~0.0002M, The compositions of various hydrolysis products obtained by means of "average composition" method showed that trinualear species are predominant and that the number of OH- bound to each ohromiumion increased when the concentration of the ion decreased or/and the pH increased. The hydrolysis constants of the ions of the same degree of polymerization abtained at different concentrations were found to be very consistent with each other, and the β43 is in agreement with that obtained in Part Ⅰ of this series of studies. Tho composition presented in this paper is also consistent with the charges on the polynualear nations as determined by means of the coagulation value mothod.