化学学报 ›› 1981, Vol. 39 ›› Issue (3): 209-213. 上一篇    下一篇

论文

没食子酸锑钠的化学结构研究

应慧卿   

  1. 南京药物研究所
  • 投稿日期:1977-05-07 发布日期:2013-06-03

STUDIES ON THE CHEMICAL STRUCTURE OF SODIUM ANTIMONY GALLATE

YING HUI-QING   

  1. Nanjing Institute of Materia Medica
  • Received:1977-05-07 Published:2013-06-03

没食子酸锑钠[二没食子酸-(3,4)-亚锑酸三钠,简称锑-273]是一种有效的抗血吸虫病药物.本文用衍生物合成、降解反应、红外光谱、核磁共振谱及X-射线衍射晶体分析法研究了它的化学结构.组成式C14H6O10SbNa3·H2O,基本骨架是每个锑原子与四个氧原子和一分子水形成配位数为5的锑氧络合中心离子.

Sodium antimony gallate (trisodium digallate-(3, 4)-antimonite, Sb-273) is an effective schistosomicide. Its structure has been studied through a series of chemical synthesis, preparation of derivatives, degradations and IR analyses, and ultimately determined by X-ray diffraction. It is a complex salt with the molecular formula C14H6O10SbNa3·H2O which is formed through the coordination of four oxygen atoms and a water molecule to each antimony atom. The latter serves as a central atom in the complex anion.