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化学学报
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化学学报 ›› 1980, Vol. 38 ›› Issue (5): 484-488. 上一篇    下一篇

研究简报

氯硅烷的醇解反应及硅烷偶联剂的合成

吴观丽, 王夺元, 戴道荣, 谢祖璹, 孙红, 吴冶新   

  1. 中国科学院化学研究所 北京
  • 投稿日期:1978-07-31 发布日期:2013-06-03

THE ALCOHOLYSIS OF CHLOROSILANES AND THE SYNTHESIS OF SILANE COUPLING AGENTS

WU GUAN-LI, WANG DUO-YUAN, DAI DAO-RONG, XIE ZU-SHOU, SUN HONG, WU YE-XIN   

  1. Institute of Chemistry, Academia Sinica, Beijing
  • Received:1978-07-31 Published:2013-06-03

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1505

被引次数

38

前文报道了硅氯仿(HSiCl3)的甲醇解反应.本工作为此反应的继续,把它推广到其它氯硅烷的醇解上,收到了同样的好效果.醇解产率都在90%以上.

A compound 2 corresponding to C;,-N fragment of maytansine has been spnthe-sized.Starting from 2-methogy-(i-nitroaniline(3),4-Chloro-3-methoxy-5-methyl-aminobenzaldehyde(11) was prepared through sig steps,the position of bromine in 4 heing proved by means of NMR.