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化学学报
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化学学报 ›› 1979, Vol. 37 ›› Issue (1): 67-70. 上一篇    下一篇

研究简报

有机化合物结构与性能间的关系对联多苯和间联多苯

赵学庄, 高振衡   

  1. 南开大学化学系
  • 投稿日期:1977-12-12 发布日期:2013-06-03

RELATIONSHIP BETWEEN MOLECULAR STRUCTURES AND PROPERTIES OF ORGANIC COMPOUNDS——PARA-AND META-POLYPHENYLS

CHAO HSUEH-CHUANG, KAO CHEN-HENG   

  1. Department of Chemistry, Nankai University
  • Received:1977-12-12 Published:2013-06-03

PDF

782

被引次数

4

关于对位联多苯的电子光谱[1,2]Lewis[3]认为是属于“两类典型线摆动体”以外的一个“中间类型”,而Ferguson[4]认为是“第一类共轭体系”的一个例外,电子光谱不能用λ2∝n或λ∝n这两个典型公式来表示.

The HOMO energies(εH)of pare-and mete-polyphenyls are calcalated with the graph theory of molecular orbitals.The εH and the wavo numbers (v) of maximum absorption bands follow the rule of homologoas linearity, but the variations of εH and v are more considerable for pare-polyphenyls than for mete-isomers.