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化学学报
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化学学报 ›› 1976, Vol. 34 ›› Issue (3): 179-196. 上一篇    下一篇

论文

龙舌兰属植物中甾族皂甙元的研究——Ⅱ.剑麻中甾族皂甙元的分离和鉴定

丛浦珠, 陈延镛, 黄量   

  1. 中国医学科学院药物研究所
  • 投稿日期:1975-09-01 发布日期:2013-06-03

STUDIES ON THE STEROIDAL SAPOGENINS OF AGAVE PLANT——Ⅱ.ISOLATION AND IDENTIFICATION OF THE STEROIDAL SAPOGENINS FROM LEAVES OF AGAVE SISALANA PERRINE

CONG PU-CHU, CHEN YEN-YONG, HUANG LIANG   

  1. Institute of Materia Medica, Chinese Academy of Medical Sciences
  • Received:1975-09-01 Published:2013-06-03

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973

被引次数

17

从海南岛栽培的剑麻叶中分离出10个已知的甾族化合物,即新替告皂甙元酮(Ⅱ,Neo-tigogenone)、β-谷甾醇(Ⅴ,β-Sitosterol)、新替告皂甙元(Ⅵa,Neotigogenin)、替告皂甙元(Ⅵb,Tigogenin)、剑麻皂甙元(Ⅶa,Sisalagenin)、海柯皂甙元(Ⅶb,Hecogenin)、5α-娠烷-3β、20β-二醇(Ⅸ,5a-Pregnan-3β,20β-diol)、洛柯皂甙元(Ⅹ,Rockogenin)、12-表洛柯皂甙元(ⅩⅠ,12-Epirockogenin)和绿莲皂甙元(ⅩⅥ,Chlorogenin)以及两个新的三羟基甾族皂甙元,即海南皂甙元(Hainangenin)和红光皂甙元(Hongguanggenin),根据质谱和核磁共振谱,这两个新皂甙元的结构初步分别定为3β,6α,23β-三羟基-5α,25R-螺甾烷(ⅩⅧa)和3β,6α,23α-三羟基-5α,25R-螺甾烷(ⅩⅧb),两者为C23位的差向异构体.

Ten known steroidal compounds, namely, Neotigogenone (Ⅱ),β-Sitosterol (Ⅴ), Neotigogenin (Ⅵa),Tigogenin (Ⅵb),Sisalagenin ( VIIa),Hecogenin (VIIb),5a-Preg-nan-3,β, 20β-diol (Ⅸ),Rockogenin (Ⅹ),12-Epirockogenin (ⅩⅠ) and Chlorogenin (ⅩⅥ) and two new trihydrogysapogenins, Hainangenin and Hongguanggenin, were isolated from the leaves of Agave sisalana Perrine gathered from Haitian.