化学学报 ›› 1975, Vol. 33 ›› Issue (2): 101-112. 上一篇    下一篇

论文

电负性与若干原子结构参数的关系

陈念贻, 章兴国   

  1. 中国科学院上海冶金研究所
  • 投稿日期:1974-12-27 发布日期:2013-06-03

ON THE RELATIONSHIP BETWEEN ELECTRONEGATIVITY AND SOME PARAMETERS OF ATOMIC STRUCTURE

CHEN NIAN-YI, CHANG HSING-KUO   

  1. Shanghai Institute of Metallurgy, Academia Sinica
  • Received:1974-12-27 Published:2013-06-03

本文考查了Pauling电负性与价电子静电位能的表征参数(电荷与半径比),以及内层电子分布概率密度径向衰减的表征参数R0/rcov、p(rcov)等的关系.求得用z*/rcov、R0/rcov等计算电负性的经验公式.在此基础上设计了新的键参数作图方法.讨论了电负性的物理意义和有关认识论的一些问题.

This paper deals with the physical and philosophical concepts of eleotronegativity.Some diagrammatic methods,using the ciharge-radius ratio and electronegativity as parameters,are described.It appears that the electronegativity scale,which often fails when used alone,can be applied to solve some practical problems successfully when it is used in combination with the charge-radius ratio.The relationship of electronegativity scale to the charge-radius ratio and some other parameters describing the radial distribution of inner electrons,such as R0cov and ρ(rcov),has been investigated.Some empirical equations are proposed,and the physical meaning of the relationship is discussed.