化学学报 ›› 1966, Vol. 32 ›› Issue (1): 103-105. 上一篇    

研究简报

磷酸锡的离子交换性质——Ⅰ.某些金属离子的纸层析

殷伯海, 朱永祥   

  1. 西北大学化学系
  • 投稿日期:1965-04-19 发布日期:2013-06-03

ION EXCHANGE PROPERTIES OF STANNIC PHOSPHATE——Ⅰ. CHROMATOGRAPHIC BEHAVIOUR OF SOME CATIONS ON PAPER IMPREGNATED WITH STANNIC PHOSPHATE

YING Bo-Hai, CHU Yung-Hseing   

  1. Department of Chemistry, Northwestern University
  • Received:1965-04-19 Published:2013-06-03

Inoue曾研究磷酸锡的离子交换性质,耐高温和抗辐射性等性质和用柱式操作分离过裂变产物[1,2].本文将磷酸锡固着于新华滤纸作成离子交换纸,以不同浓度的盐酸、硝酸、硫酸、高氯酸和醋酸溶液为展开剂,测定二十八种金属离子的比移值,和找出部分金属离子的分离最佳条件.

The chromatographic behaviour of 28 inorganic cantions on stannic phosphate paper has been investigated.Ascending development was used with 0.1 to 4 N hydrochloric,nitric,sulphuric,and perchloric acids solutions as eluents.The results obtained indicate that this method may be successfully employed for the chromatographic separations of many catrons.