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化学学报 ›› 1964, Vol. 30 ›› Issue (6): 577-581. 上一篇 下一篇
研究简报
高孟明
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GAO MONG-MING
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廿多年来许多作者提出各种计算电负性的方法,但所求得的各原子电负性数值,均不尽一致.不幸的是目前尚无法直接由实验测定电负性,很难判断那一种计算方法较为合理.此外,多位作者尚对中性原子的轨道电负性、键的电负性以及自由基的电负性、原子团的电负性进行计算.
In this paper,it is suggested to use the mean effective attraction force exerted on the valence electrons by the atoms as a basis for the calculation of electronegativity.Taking the orbital function of hydrogen-like atom as the wroth-order approximate wave function of many-electron atoms,the present author derived a Formula for calculating electronegativities of atoms,which can also be applied to atoms in various valence states.With a few exceptions,all results obtained are close to those published in literature.
高孟明. 原子电负性的一种计算方法[J]. 化学学报, 1964, 30(6): 577-581.
GAO MONG-MING. A METHOD FOR CALCULATING THE ATOMIC ELECTRONEGATIVITIES[J]. Acta Chimica Sinica, 1964, 30(6): 577-581.
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