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化学学报
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化学学报 ›› 1964, Vol. 30 ›› Issue (5): 471-477. 上一篇    下一篇

论文

有机磷化合物的研究 Ⅱ.烷基磷酸的紙层析和紙电泳分离法

陸熙炎, 叶功新, 袁承業   

  1. 中国科学院有机化学研究所
  • 投稿日期:1963-11-11 修回日期:1964-03-12 发布日期:2013-06-03

STUDIES ON ORGANOPHOSPHORUS COMPOUNDS Ⅱ. SEPARATION OF ALKYLPHOSPHORIC ACIDS BY PAPER CHROMATOGRAPHY AND PAPER ELECTROPHORESIS

LUH HSI-YIEN, YE KUNG-XING, YUEN CHENG-YIH   

  1. Institute of Organic Chemistry, Academia Sinica
  • Received:1963-11-11 Revised:1964-03-12 Published:2013-06-03

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544

被引次数

2

1.纸层析适宜于分离相同烷基的一烷基磷酸和二烷基磷酸。二烷基磷酸的比移值一般大于一烷基磷酸。比移值随碳原子数而增大。2.纸电泳适宜于分离同一类型而碳原子数不同的烷基磷酸,其泳动值随碳原子数之增大而变小。和纸层析相反,一烷基磷酸的泳动值大于二烷基磷酸。改变缓冲液中有机溶剂的含量可改变长碳键二烷基磷酸的泳动值。

Systematic study on the separation of monoalkyl- and dialkyl phosphoric acids with C1-C3 carbon atoms in the ester alkyl group by paper chromatography and paper electro-phoresis has been made for the purpose of studying the relationship between chemical structure and physical properties.