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化学学报
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化学学报 ›› 1964, Vol. 30 ›› Issue (2): 135-138. 上一篇    下一篇

论文

有色高聚物Ⅰ.含偶氮基的丙烯酸酯及酰胺的制备与聚合

蒋德彰, 伍少兰   

  1. 北京大学化学系
  • 投稿日期:1963-04-08 发布日期:2013-06-03

COLORED POLYMERS Ⅰ. PREPARATION AND POLYMERIZATION OF AZO-GROUP CONTAINING ACRYLIC ESTERS AND AMIDES

CHIANG TEH-CHANG, WU SHAO-LAN   

  1. Department of Chemistry, Peking University
  • Received:1963-04-08 Published:2013-06-03

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已制备丙烯酸及甲基丙烯酸偶氮苯酯(Ⅰ,Ⅱ),N-偶氮苯基丙烯酰胺及甲基丙烯酰胺(Ⅲ,Ⅳ)等四种含偶氮基的有色化合物.这些化合物能均聚反应,亦易与苯乙烯、甲基丙烯酸甲酯及丙烯腈等乙烯类单体共聚合,得有色的高聚物.

4-Benzeneazophenyl acrylate and methacylate (Ⅰ,Ⅱ),N-4-benzeneazophenyl acrylamide and methacrylamide (Ⅲ,Ⅳ) have been prepared by the reaction of 4-hydroxy-azobenzene and 4-aminoazobenzene with acrylic or methacrylic chloride in the presence of triethylamine.These colored compounds can be homopolymerized and copolymerized with most vinyl monomers such as styrene,methyl methacrylate and acrylonitrile,to give the corresponding colored polymers.