化学学报 ›› 1961, Vol. 27 ›› Issue (2): 160-162. 上一篇    下一篇

醇钠与二烷基亚磷酸酯和四氯化碳的反应及其产物三烷基正磷酸混合酯

童曾寿   

  • 投稿日期:1959-12-22 发布日期:2013-06-03

PREPARATION OF MIXED ESTERS OF TRIALKYL ORTHO-PHOSPHORIC ACID BY THE REACTION OF SODIUM ALCOHOLATE WITH DIALKYLPHOSPHITES AND CARBON TETRACHLORIDE

TUNG TZENG-SHOU   

  • Received:1959-12-22 Published:2013-06-03

作者前[1,2]用下法制取磷酰苯胺酯类(Ⅱ)时,为阐明二烷基亚磷酸酯(Ⅰ)中烷基结构和辅助剂叔胺的碱性强弱的影响,曾进行一些研究[2].现在认为对辅助剂的碱性和反应的关系,还有必要作更进一步的补充.

In this paper, the influence of the basicity of auxiliary bases on the reaction of dialkyl-phosphites (Ⅰ) and carbon tetrachloride with aniline has been discussed.The mixed esters of trialkylorthophosphoric acid (Ⅲ) are prepared in good yield by the reaction of sodium alcoholate with dialkylphosphites and carbon tetrachloride.