化学学报 ›› 1959, Vol. 25 ›› Issue (1): 73-80. 上一篇    

论文

脂肪酸钠盐对正戊酸在水中溶度的影响

杨文治, 胡瑶村, 宋果男, 黄子卿, 雷鸿毅   

  1. 北京大学化学系
  • 投稿日期:1958-11-24 发布日期:2013-06-03

THE SOLUBILITIES OF n-VALERIC ACID IN AQUEOUS SALT SOLUTIONS OF SODIUM SALTS OF PATTY ACIDS

YANG WEN-CHEH, HU YAO-CHUN, SUNG KUO-NAN, HUANG TZU-CHING, LEI HUNG-YI   

  1. Department of Chemistry, Peking University
  • Received:1958-11-24 Published:2013-06-03

作者测定在25℃下正戊酸在十种脂肪酸钠盐(甲、乙、丙、正丁、正戊、正己、正庚、正辛、正壬、正癸酸钠)的水溶液中的溶度。甲、乙、丙、丁酸钠的作用是盐溶;己、庚、辛、壬癸酸钠的作用是盐析。戊酸钠的作用,在低浓度时是盐析,高浓度时转为盐溶。除具同离子效应的戊酸钠外,我们主要用正戊酸对脂肪酸钠的排代反应和排代出的新酸在水相和正戊酸相的分布来解释正戊酸溶度的变化。

Huang and Yang[1] studied the effect of five cobalt ammtnes on the solubilities of n-valeric acid in water. These salts salt out the acid, and the amount of salting-out increases with the increase of the charge of the canon. Later, Li and Huang[2] studied the activity coefficients of n-phthalene in seven salts (sodium formats to sodium n-heptylate) of fatty acids and found with the increase of number of carbon atoms in the salts, the salting-ont, of n-phthalene decreases, changes into salting-in, which then continues to increase. But the same five aalt.s (sodium forznate to sodium n-valernte) prodnce an irregnlnr effect of salting-in of caproic acid[3].