化学学报 ›› 1957, Vol. 23 ›› Issue (6): 421-427. 上一篇    下一篇

论文

迎头色谱法测定气体吸附等温线

G. SCHAY, G. SZÉKELY, P. FEJES   

  1. 布达佩斯工业大学物理化学系
  • 投稿日期:1957-03-03 发布日期:2013-06-03

DETERMINATION OF ADSORPTION ISOTHERMS OF GASES BY FRONTAL CHROMATOGRAPHY

G. SCHAY, G. SZÉKELY, P. FEJES   

  1. Institute of Physical Chemistry, Technical University, Budapest
  • Received:1957-03-03 Published:2013-06-03

本文利用一种新的气体迎头色譜法,測定純气体和气体混合物的吸附等温綫,这方法的基础是測量和比較气体进入吸附柱的速度和从吸附柱出来的速度。吸附气体代替原来填充在吸附柱内的惰性气体时,到吸附气体透过时的出来的气体体积即表示仪器的死空間,所以死空間就不必另外測定。

The general interest in the theoretical and practical study of the adsorption of gases and vapours in flo+r systems,in contrast to the classical static methods,is steadily increasing.It soems that mainly the spreading of contact catalytical industrial processes requires roliable adsorption and reaction kinetical measurements on the same flow systems,under possibly identical conditions of flow,pressure and femperature.Sipco tlio earlier dynar}ica,l methods for measuring adsorption wero appreciably less precise than the static ones,they were applied but to a little oxtent.However,recent developments in chromatography,and mainly in gas chromatography,made it possible to)volve quite sensitive dynamical methods of measurement.