化学学报 ›› 1955, Vol. 21 ›› Issue (3): 227-231. 上一篇    下一篇

论文

贝母植物硷研究Ⅱ.贝母素甲及乙的再研究

朱子清1,2, 陆仁荣1,2   

  1. 1. 中国科学院有机化学研究所;
    2. 復旦大学化学系
  • 投稿日期:1955-04-09 发布日期:2013-06-04

A STUDY OF FRITILLARIA ALKALOIDS Ⅱ. FURTHER STUDY OF PEIMINE AND PEIMININE

CHU TZE-TSIN(T. T. CHU)1,2, LOH JEN-YUNG1,2   

  • Received:1955-04-09 Published:2013-06-04

1.修正貝母素甲及貝母素乙的實驗式順次為C27H45O3N及C27H43O3N.2.貝母素甲及乙分子中證明不合甲氧基或乙氧基,亦不合甲氮基或乙氮基,亦無活潑>C=C<鍵及叔醇羥基,二者皆至少含有三個甲碳基.貝母素乙分子中未能找出活潑次甲基的存在.3.製備了貝母素甲的硫氰酸鹽,貝母素乙的硫氰酸鹽,及貝母素乙的碘甲季銨鹽.4.貝母素甲用硒脫氫,得鹼性產物四種:C25H37N,苦味酸鹽熔點220°;C26H37N,苦味酸鹽熔點193°;C26H37O2N,熔點228°;C26H41O3N,熔點256°.

The empirical formulae of peimine and peiminine are revised to C27H45O3N and C27H43O3N respectively.Neither peimine nor peiminine has a methoxyl or ethoxyl group, a methylimino or ethylimino group, or probably a tertiary alcoholic hydroxyl group.Their basic tertiary nitrogen atomis probably present in the bicyclic ring.Peimine or peiminine has no active ethylenic linkage, and the active methylene group adjacent to the carbonyl group of peiminine seems to be absent.Both peimine and peiminine contain at least three carbon-methyl groups and give no sparingly soluble digitonide.