化学学报 ›› 1955, Vol. 21 ›› Issue (3): 247-252. 上一篇    下一篇

论文

苯二酸二丁酯对于聚甲基丙烯酸甲酯的软化温度影响

朱秀昌, 曹家桢   

  1. 中国科学院有机化学研究所
  • 投稿日期:1955-04-15 发布日期:2013-06-04

EFFECT OF DIBUTYL PHTHALATE ON THE SOFTENING POINT OF POLYMETHYLMETHACRYLATE

CHU SHU-CHANG, TSAO CHIA-CHEN   

  1. Institute of Organic Chemisty,Academia Sinica
  • Received:1955-04-15 Published:2013-06-04

測定了不同苯二酸二丁酯含量的聚甲基丙烯酸甲酯的軟化温度、二級轉變温度和低温彈性模數,得出苯二酸二丁酯含量和軟化温度的關係式:T=112-947N.並從低温彈性模數說明添加苯二酸二丁酯後改進了聚甲基丙烯酸甲酯的低温度衝擊強度.

The softening point and Young's modulus of polymethylmethacrylate at low temperature with various contents of dibutyl phthalate have been measured by using a Höpier consistometer and a dilatometer respectively, The relationship between the molar concentration of dibutyl phthalate, N, and the softening point, T, can be expressed by the equation T=112-947N.An explanation for the difference between the coeficient 947 and the value 228-232, previously obtained by Zhurkov, is suggested.