化学学报 ›› 1955, Vol. 21 ›› Issue (3): 273-279. 上一篇    下一篇

论文

高频滴定曲缐

钱人元   

  1. 中国科学院有机化学研究所
  • 投稿日期:1955-04-11 发布日期:2013-06-04

ON THE HIGH-FREQUENCY TITRATION CURVES

CHIEN JEN-YUAN   

  1. Institute of Organic Chemistry,Academia Sinica
  • Received:1955-04-11 Published:2013-06-04

1.對高頻滴定用的C式和L式滴定池,Q表法,Z表法及F表法测定得到的滴定曲線,與溶液電導改變的關係,用等效電路的理論,作了全面的討論.除C式滴定池Q表法測定,文獻中已有討論外,L式滴定池Q表法測定時,和C式滴定池Z表法和F表法測定時,滴定過程中測定的量都與溶液的電導值單調變化.2.指出了文獻中的錯誤.C式滴定池應用等效串聯電路與等效並聯電路計算的結果,是完全等同的.C式滴定池的高頻電能損耗與溶液中電解質濃度的關係,與Debye-Falkenhagen效應無關.3.提出了用鉑絲電極直接插入溶液的高頻滴定法.

High-frequenry titration curves are discussed for various methods of experimental determination(the Q-meter, Z-meter and F-meter methods), using equivalent circuits for C-type and L-type titrating cells.It has been found that for the cases of L-type cell with Q-determination and C-type cell with Z- or F-determination, the quantity measured in the course of titration changes monotonously with the increase of conductivity of the solution.In these cases, the high-frequency titration curve should be similar in shape to that obtained in an ordinary conductometric titration.Two mistakes appearing in literature are here pointed out.