化学学报 ›› 1954, Vol. 20 ›› Issue (2): 144-147. 上一篇    下一篇

论文

二苯基碳醯二肼和钨钼酸根反应的灵敏度

梁树权   

  1. 中国科学院有机化学研究所
  • 投稿日期:1954-08-13 发布日期:2013-06-04

THE SENSITIVITY OF DIPHENYLCARBAZIDE TEST FOR MOLYBDATE AND TUNGSTATE IONS

LIANG SHU-CHUAN   

  1. Institute of Organic Chemistry, Academia Sinica
  • Received:1954-08-13 Published:2013-06-04

本文报告在中性溶液中,对称-二苯基碳酰二胼对钨、钼的灵敏度,两者都是1:5×107,或以0.1[D]5表示之。钨、钼酸根的灵敏度随溶液中氢离子的多寡而不同。

Lecocq first found that the sensitivity of diphenylcarbazide test for molybdate ions in mineral acid medium was 1:2.6×105 (it is assumed that he used commercial ammonium molybdate), and Schmitz-Dumont reported a value of 1:2×106 in acetic acid solution. In the present investigation, it is found that the sensitivity is still higher (1:5×107) when the test is carried out in the neutral medium (and in test tubes with an inner diameter of 10 mm). Evidently the sensitivity is greatly influenced by the concentration of hydrogen ions. The use of the diphenylcarbazide as a qualitative reagent for tungstate ions has not yet been recorded before. It is found that in the neutral medium the sensitivity of the test is 0.1 [D]5, which is the same as that for molybdate under similar conditions.