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化学学报
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化学学报 ›› 2004, Vol. 62 ›› Issue (3): 288-294. 上一篇    下一篇

研究论文

meso,β-和β,β-全氟醚基磺酸酯桥连双卟啉的合成

曾卓1, 金利美2, 郭灿城1, 陈庆云1,2   

  1. 1. 湖南大学化学化工学院, 长沙, 410082;
    2. 中国科学院上海有机化学研究所有机氟化学重点实验室, 上海, 200032
  • 投稿日期:2003-09-11 修回日期:2003-12-10 发布日期:2014-01-26
  • 通讯作者: 陈庆云,E-mail:chenqy@mail.sioc.ac.cn E-mail:chenqy@mail.sioc.ac.cn
  • 基金资助:
    国家自然科学基金(Nos.29972051,D20032010)资助项目.

Synthesis of meso,β-and β,β-Perfluoroetherylsulfonyl Ester Linked Diporphyrins

ZENG Zhuo1, JIN Li-Mei2, GUO Can-Cheng1, CHEN Qing-Yun1,2   

  1. 1. College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082;
    2. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
  • Received:2003-09-11 Revised:2003-12-10 Published:2014-01-26

PDF

429

被引次数

13

β-氟砜基全氟醚基取代四芳基卟啉与5-(4-羟苯基)-10,15,20-三苯基卟啉、BINOL反应分别生成meso,β-和β,β-全氟醚基磺酸酯桥连双卟啉,双卟啉与醋酸锌在CHCl3/CH3OH中回流可高产率获得双锌卟啉,测定并讨论了meso,β-和β,β-全氟醚基磺酸酯连接双卟啉的紫外可见和荧光光谱.

关键词: β-氟砜基全氟醚基取代四芳基卟啉, meso,β-双卟啉, β,β-双卟啉, 紫外可见光谱

β-Fluorosulfonylperfluoroetheryltetraaryl porphyrins reacted with 5-(4-hydroxyphenyl)-10,15,20-triphenylporphyrin and BINOL to afford meso,β-or β,β-perfluoroetherylsulfonyl ester linked diporphyrins.Treatment of the diporphyrins with zinc acetate in CHCl3/CH3OH under refluxing for 1 h gave diporphinatozinc.UV-vis absorption and fluorescence data of meso,β- andβ,β-diporphyrins were determined and discussed.

Key words: β-fluorosulfonylperfluoroetheryltetraaryl porphyrin, meso, β-diporphyrins, β, β-diporphyrins, UV-vis