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化学学报
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化学学报 ›› 2004, Vol. 62 ›› Issue (7): 680-685. 上一篇    下一篇

研究论文

用AFM研究阳极氧化铝的不稳定生长

孔令斌1, 陈淼2, 力虎林1   

  1. 1. 兰州大学化学化工学院, 兰州, 730000;
    2. 中国科学院兰州化学物理研究所固体润滑国家重点实验室, 兰州, 730000
  • 投稿日期:2003-03-07 修回日期:2003-10-14 发布日期:2014-02-18
  • 通讯作者: 力虎林,E-mail:lihl@lzu.edu.cn E-mail:lihl@lzu.edu.cn
  • 基金资助:
    国家自然科学基金(No.60171004)资助项目.

Unstable Growth of Anodic Aluminum Oxide Investigated by AFM

KONG Ling-Bin1, CHEN Miao2, LI Hu-Lin1   

  1. 1. College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000;
    2. State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000
  • Received:2003-03-07 Revised:2003-10-14 Published:2014-02-18

PDF

443

被引次数

78 | 3

用原子力显微镜(AFM)研究了多孔阳极氧化铝(AAO)模板的不稳定生长. 结果表明:AAO模板的不稳定生长导致了纳米孔道结构有序度的降低.在H3PO4溶液中生长的AAO模板孔道结构稳定性较差;而在H2C2O4溶液中生长的AAO模板稳定性依赖于氧化电压和电流密度,在低电压和电流密度下稳定性较好,高电压和电流密度下稳定性较差. 充分利用这种不稳定生长特性,通过控制AAO模板的阳极氧化条件,可得到具有分枝孔道结构的特殊模板,这为利用模板法制备各种Y形或T形纳米线、管提供了新的发展空间.

关键词: 原子力显微镜(AFM), 阳极氧化铝(AAO), 不稳定生长, 分枝结构

Atomic force microscope (AFM) was utilized to investigate the unstable growth of porous anodic aluminum oxide (AAO) membrane. The results showed that the unstable growth of AAO membrane resulted in the decrease of the order degree of its special nano-channels. The AAO membrane growing in H3PO4 solution is unstable, while the growth stability in H2C2O4 solution will depend on its anodized voltage and current density: stable in low voltage and low current density while unstable in high voltage and high current density. By controlling the condition of the anodized process, the special AAO template with branched channel structures can be formed because of the unstable growth of the membrane. This may provide a new opportunity for fabricating Y-shape or T-shape nanowires and nanotubes by using the template method.

Key words: atomic force microscope, anodic aluminum oxide, unstable growth, branched structure