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化学学报
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化学学报 ›› 2004, Vol. 62 ›› Issue (13): 1205-1210. 上一篇    下一篇

研究论文

硼酸根插层水滑石层间组成及取向结构的控制

李素锋, 李殿卿, 史翎, 杨兰, 蒲敏, Evans D. G., 段雪   

  1. 北京化工大学可控化学反应科学与技术基础教育部重点实验室, 北京, 100029
  • 投稿日期:2003-09-18 修回日期:2004-01-16 发布日期:2014-02-17
  • 通讯作者: 段雪,E-mail:duanx@mail.buct.edu.cn E-mail:duanx@mail.buct.edu.cn
  • 基金资助:
    国家自然科学基金重点(No.90306012)资助项目.

Control of Interlayer Composition of Borate Pillared LDHs by Varying pH of Intercalation

LI Su-Feng, LI Dian-Qing, SHI Ling, YANG Lan, PU Min, EVANS D. G., DUAN Xue   

  1. Key Laboratory of Science and Technology of Controllable Chemical Reactions, Ministry of Education, Beijing University of Chemical Technology, Beijing 100029
  • Received:2003-09-18 Revised:2004-01-16 Published:2014-02-17

PDF

437

被引次数

29

以Mg0.67Al0.33(OH)2(CO3)0.165·0.62H2O LDHs为前体,以水为分散介质,由离子交换法组装了硼酸根插层LDHs,并用XRD,FT-IR,TG-DTA,ICP,11B MAS NMR等手段对样品进行了分析和表征.结果表明,通过控制离子交换时的pH,可使硼酸根取代Mg-Al-CO3 LDHs前体层间的CO3-,且可控制离子交换程度及客体的取向,从而控制插层结构.对硼酸根插层LDHs的结构进行研究发现,控制pH=4.5,层间阴离子主要是一硼酸根和离子平面与LDHs层板平行的三硼酸根,出于结构稳定的需要,CO3-不能完全被置换;控制pH=3.5,层间阴离子是一硼酸根和离子平面与LDHs层板垂直的三硼酸根.

关键词: LDHs, 硼酸, pH, 硼酸根插层LDHs

Borate pillared layered double hydroxides (LDHs) have been prepared by an ion-exchange method with Mg0.67Al0.33(OH)2(CO3)0.165·0.62H2O being the precursor.The samples were analyzed by XRD, FT-IR, TG-DTA, ICP and 11B MAS NMR.The results showed that by controlling the pH of the ion-exchange medium, borate ions can substitute carbonate ions in the interlayeres.Furthermore, the extent of ion exchange and the nature of the guest ions can be used to control the structure of the products.When the pH of the reaction mixture is 4.5, the interlayer anions are mainly monoborate anions and triborate anions with the plane of the latter being parallel to the layers of the LDHs.Under these conditions carbonate anions are not completely replaced.When the pH value is 3.5, monoborate anions and triborate anions with the plane of the latter being perpendicular to the layers are mainly present in the interlayer galleries.

Key words: LDHs, boric acid, pH, borate-pillared LDHs