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化学学报
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化学学报 ›› 2004, Vol. 62 ›› Issue (19): 1859-1861.    下一篇

研究通讯

以SBA-16为模板电沉积生长多孔氧化铁纳米线阵列

史克英, 辛柏福, 池玉娟, 付宏刚   

  1. 黑龙江大学化学化工与材料学院物理化学实验室, 哈尔滨, 150080
  • 投稿日期:2004-03-12 修回日期:2004-06-14 发布日期:2014-02-17
  • 通讯作者: 付宏刚,E-mail:fuhg@vip.sina.com E-mail:fuhg@vip.sina.com
  • 基金资助:
    国家自然科学基金(Nos.20171016,20301006)、黑龙江省杰出青年科学基金(2002)和黑龙江省博士后基金(2004)资助项目.

Assembling Porous Fe2O3 Nanowire Arrays by Electrochemical Deposition in Mesoporous Silica SBA-16 Films

SHI Ke-Ying, XIN Bai-Fu, CHI Yu-Juan, FU Hong-Gang   

  1. School of Chemistry and Science Materials, Physical Chemistry Laboratory, Heilongjiang University, Harbin 150080
  • Received:2004-03-12 Revised:2004-06-14 Published:2014-02-17

PDF

525

被引次数

34

采用电化学沉积法以Mn改性的三维体心立方结构的介孔SBA-16膜为模板制备Fe纳米线.沉积Fe后的SBA-16膜以2%HF溶解SiO2骨架,样品于550℃焙烧4 h.SEM和TEM的研究结果显示,所制备的Fe2O3纳米线互相平行,孔径均匀.XRD、电子衍射及HRTEM研究表明Fe2O3纳米线具有(多孔)单晶结构.

关键词: SBA-16膜, 电沉积Fe, 多孔Fe2O3纳米线

Fe nanowire arrays were prepared by electro-deposition using 3D Mn-doping SBA-16 film. Fe-deposited SBA-16 film was treated with a 2% HF aqueous solution to remove the SiO2 template. The specimen was calcined in air at 550℃ for 4 h. Both SEM and TEM results indicate that the nanowires are paralleled with each other and have uniformed diameter. XRD, electron diffraction and HRTEM investigations demonstrate that the crystalline structures of these nanowires are porous crystal of iron oxide.

Key words: SBA-16 film, electrodeposition of Fe, porous Fe2O3 nanowire