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化学学报
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化学学报 ›› 2024, Vol. 82 ›› Issue (8): 871-878.DOI: 10.6023/A24040144 上一篇    下一篇

研究论文

Zn, C引入量和煅烧温度对ZnO/C/CeO2光催化还原Cu2+效率的影响

张帆帆†, 蔡元韬†, 陶剑波†, 常国菊, 郭欣辰, 郝仕油*()   

  1. 浙江师范大学行知学院 化学与材料科学学院 金华 321004
  • 投稿日期:2024-04-25 发布日期:2024-07-22
  • 作者简介:
    † 共同第一作者
  • 基金资助:
    国家自然科学基金(21876158); 浙江省金华市重点科技项目(2022-1-077); 浙江省新苗人才计划(2023R404052)

Effect of Zn, C Introduction Amount and Calcination Temperature on the Photocatalytic Reduction of Cu2+over ZnO/C/CeO2

Fanfan Zhang†, Yuantao Cai†, Jianbo Tao†, Guoju Chang, Xinchen Guo, Shiyou Hao*)   

  1. Xingzhi College, College of Chemistry and Materials Science, Zhejiang Normal University, Jinhua 321004, Zhejiang Province, China
  • Received:2024-04-25 Published:2024-07-22
  • Contact: * E-mail: sky54@zjnu.cn
  • About author:
    † These authors contributed equally to this work
  • Supported by:
    National Natural Science Foundation of China(21876158); Key Science and Technology Projects in Jinhua City of Zhejiang Province(2022-1-077); Zhejiang Province New Talent Plan(2023R404052)

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以Ce(NO3)3•6H2O和Zn(NO3)2•6H2O为金属源, 酸性红14 (AR14)为碳源, 通过共沉积法制备了Zn(OH)2/AR14/Ce(OH)4前驱体, 在惰性气体中煅烧前驱体获得ZnO/C/CeO2材料. 采用X射线衍射、扫描电子显微镜、红外光谱、光致发光、X射线光电子能谱等技术对合成材料进行了表征, 结果表明, 所得材料中Zn、Ce、C分布均匀, 在CeO2中引入Zn和C有利于氧空位和碳键形成, 促进光电子和空穴有效分离, 从而提高产物光催化活性. 通过Cu2+还原考察了主要合成参数对ZnO/C/CeO2光催化活性的影响, 结果表明, 当反应原料中Zn(NO3)2•6H2O加入量为0.5 g, AR14浓度为0.05 mmol/L, 煅烧温度为350 ℃时, 所制备的ZnO/0.05C/2CeO2对Cu2+的光催化还原效率最好, 达到95.34%.

关键词: ZnO/C/CeO2, Cu2+, 光催化还原, 氧空位, 电子-空穴对

In this study, the Zn(OH)2/AR14/Ce(OH)4 precursor was prepared by a co-deposition method using Ce(NO3)3•6H2O as the cerium source, Zn(NO3)2•6H2O as the zinc source, and acidic red 14 (AR14) as the carbon source. Then, ZnO/C/CeO2 materials were obtained by calcination of the precursor in a tube furnace under N2 atmosphere at different temperatures. The composite was characterized by X-ray diffraction, scanning electron microscope, Fourier transform infrared spectroscopy, photoluminescence and X-ray photoelectron spectroscopy. The results showed that the ternary composites were prepared successfully, and that the carbon existed in an amorphous form. Due to the thermal decomposition of the precursor at high temperatures, the synthesized products exhibit porous property. Due to the uniform distribution of reactants in the reaction system, the distribution of Zn, Ce and C in the obtained material was uniform. It can be seen that the introduction of Zn and the formation of Ce3+ in CeO2 are conducive to the formation of oxygen vacancies, generating intermediate energy levels and thus broadening the light absorption range. Furthermore, oxygen vacancies can easily capture photoelectrons and thus accelerate their separation from holes in the value band, which can improve the photocatalytic efficiency of the resulted materials. The introduction of C into CeO2 can produce a certain amount of carbon bonds, promote the effective separation of photoelectrons and holes, and improve the photocatalytic activity of the product. The effects of the amount of introduced Zn and C and the calcination temperature on the photocatalytic activity of ZnO/C/CeO2 were investigated by the photocatalytic reduction of Cu2+. The results showed that when the amount of Zn(NO3)2•6H2O in the reaction raw material was 0.5 g, the concentration of AR14 was 0.05 mmol/L, and the calcination temperature was 350 ℃ for the precursor, the photocatalytic reduction efficiency of Cu2+ over ZnO/C/CeO2 is the highest, reaching 95.34%. The main reasons for the best photocatalytic performance are the highest oxygen vacancy concentration and maximum number of carbon bonds in ZnO/0.05C/2CeO2-350, resulting in the highest separation efficiency of photogenerated electrons and holes.

Key words: ZnO/C/CeO2, Cu2+, photocatalytic reduction, oxygen vacancy, electron-hole pair