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2012 , Vol. 70 >Issue 12: 1412 - 1416

DOI: https://doi.org/10.6023/A1112312

研究简报

有机膦酸配合物热分解法制备三维网状形貌的偏磷酸铁

  • 陈炼 ,
  • 章莺鸿 ,
  • 周益明 ,
  • 谢孔微 ,
  • 陈煜 ,
  • 唐亚文 ,
  • 陆天虹
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  • a 江苏省新型动力电池重点实验室南京师范大学化学与材料科学学院南京 210046;
    b 南京工程高等职业学校地质工程系南京 211135

收稿日期: 2011-12-31

  修回日期: 2012-04-25

  网络出版日期: 2012-04-20

基金资助

国家自然科学基金(Nos. 21005039, 21073094)和江苏高校优势学科建设工程资助项目

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Simple and Rapid Synthesis of Fe(PO3)3 with Three-dimensional Networks Morphology by a Novel Thermal Decomposition of Iron Phosphonate

  • Chen Lian ,
  • Zhang Yinghong ,
  • Zhou Yiming ,
  • Xie Kongwei ,
  • Chen Yu ,
  • Tang Yawen ,
  • Lu Tianhong
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  • a Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210046;
    b Department of Geological Engineering, Nanjing Engineering Vocational College, Nanjing 211135

Received date: 2011-12-31

  Revised date: 2012-04-25

  Online published: 2012-04-20

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21005039 and 21073094) and the Priority Academic Program Development of Jiangsu Higher Education Institutions.

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摘要

用三氯化铁和乙二胺四甲叉膦酸(edtmpH8)为原料合成膦酸铁(FeIII-edtmpH5)配合物前驱体, 再将该前驱体在空气氛下焙烧即制得偏磷酸铁Fe(PO3)3. 利用电喷雾质谱(ESI/MS)、红外光谱(FT-IR)、热重-差热分析(TG-DTA)测试确定了FeIII-edtmpH5配合物的组成和可能结构. 对焙烧后产物进行X射线衍射(XRD)、扫描电镜(SEM)及透射电镜(TEM)测试, 结果表明焙烧产物为具有三维网状形貌的高纯Fe(PO3)3.

关键词： 偏磷酸铁; 膦酸盐; 配合物; 热分解

本文引用格式

陈炼 , 章莺鸿 , 周益明 , 谢孔微 , 陈煜 , 唐亚文 , 陆天虹 . 有机膦酸配合物热分解法制备三维网状形貌的偏磷酸铁[J]. 化学学报, 2012 , 70(12) : 1412 -1416 . DOI: 10.6023/A1112312

Abstract

The high pure Fe(PO3)3 with three-dimensional networks structure was synthesized by a novel thermal decomposition of phosphonate. Briefly, the iron phosphonate (FeIII-edtmpH5) complex was synthesized by using FeCl3 and ethylenediamine-tetramethylene phosphonic acid (edtmpH8) as starting materials. The composition and structure of FeIII-edtmpH5 complex is characterized by Fourier transform infrared spectroscopy (FT-IR), electrospray ionization/mass spectrometry (ESI/MS) and thermogravimetry-,differential thermal analysis (TG-DTA). Then, the Fe(PO3)3 is obtained by thermal decomposition of FeIII-edtmpH5 complex in air atmosphere. X-ray diffractometry (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) measurements show that the obtained Fe(PO3)3 possesses high purity, good crystallinity and particular three-dimensional networks morphology.

Key words： iron metaphosphate; phosphonate; complex; thermal decomposition

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