实验和理论研究石墨烯氧化物的铁电性
收稿日期: 2012-09-24
网络出版日期: 2013-01-09
基金资助
项目受国家自然科学基金(Nos.21071137,U1232211)资助.
Experimental and Theoretical Investigations on the Ferroelectricity of Graphene Oxides
Received date: 2012-09-24
Online published: 2013-01-09
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21071137, U1232211).
孔祥恺 , 陈乾旺 . 实验和理论研究石墨烯氧化物的铁电性[J]. 化学学报, 2013 , 71(03) : 381 -386 . DOI: 10.6023/A12090707
Graphene shows promise as a functional material in wide fields owing to its unique structures and properties. Here, as its parent material, graphene oxides have been observed exhibiting weak ferroelectric properties at room temperature. It is found that the one-dimensional hydrogen-bond chains generated by hydroxyls arranged in an orderly repeating pattern may play the key role in the electric ordering and may be responsible for this novel property of graphene oxide nano-ribbons.
Key words: ferroelectricity; graphene; graphene oxides; hydrogen-bond
[1] Geim, A. K.; Novoselov, K. S. Nat. Mater. 2002, 6, 183.
[2] Castro Neto, A. H. C.; Guinea, F.; Peres, N. M. R.; Novoselov, K. S.; Geim, A. K. Rev. Mod. Phys. 2009, 81, 109.
[3] Sharifi, F.; Bauld, R.; Ahmed, M. S.; Fanchini, G. Small 2012, 8, 699.
[4] Zheng, Y.; Ni, G. X.; Toh, C. T.; Zeng, Z. G.; Chen, S. T.; Yao, K.; Ozyilmaz, B. Appl. Phys. Lett. 2009, 94, 163505.
[5] Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Katsnelson, M. I.; Grigorieva, I. V.; Dubonos, S. V.; Firsov, A. A. Nature 2005, 438, 197.
[6] Novoselov, K. S.; Jiang, Z.; Zhang, Y.; Stormer, H. L.; Zeitler, U.; Maan, J. C.; Boebinger, G. S.; Kim, P.; Geim, A. K. Science 2007, 315, 1379.
[7] Kim, K.; Choi, J. Y.; Kim, T.; Cho, S. H.; Chung, H. J. Nature 2011, 479, 338.
[8] Bolotin, K. I. Solid State Commun. 2008, 146, 351.
[9] Wu, M. H.; Wu, X. J.; Zeng, X. C. J. Phys. Chem. C 2010, 114, 3937.
[10] Son, Y. W.; Cohen, M. L.; Louie, S. G. Nature 2006, 444, 347.
[11] Kan, E. J.; Li, Z. Y.; Yang, J. L.; Hou, J .G. Appl. Phys. Lett. 2007, 91, 243116.
[12] Stankovich, S.; Piner, R. D.; Nguyen, S. T.; Ruoff, R. S. Carbon 2006, 44, 3342.
[13] Tada, K.; Haruyama, J.; Yang, H. X.; Chshiev, M.; Matsui, T.; Fukuyama, H. Appl. Phys. Lett. 2011, 99, 183111.
[14] Liu, Z. B.; Wang, Y.; Zhang, X. L.; Xu, Y. F.; Chen, Y. S.; Tian, J. G. Appl. Phys. Lett. 2009, 94, 021902.
[15] Ahn, C. H.; Rabe, K. M.; Triscone, J. M. Science 2004, 303, 488.
[16] Horiuchi, S.; Tokura, Y. Nat. Mater. 2008, 7, 357.
[17] Xu, G. C.; Ma, X. M.; Zhang, L.; Wang, Z. M.; Gao, S. J. Am. Chem. Soc. 2010, 132, 9588.
[18] Horiuchi, S.; Tokunaga, Y.; Giovannetti, G.; Picozzi, S.; Itoh, H.; Shimano, R.; Kumai, R.; Tokura, Y. Nature 2010, 463, 789.
[19] Naber, R. C. G. Nat. Mater. 2005, 4, 243.
[20] Slater, J. C. J. Chem. Phys. 1941, 9, 16.
[21] Horiuchi, S.; Kumai, R.; Tokura, Y. Angew. Chem., Int. Ed. 2007, 46, 3497.
[22] Kumai, R.; Horiuchi, S.; Okimoto, Y. J. Chem. Phys. 2006, 125, 084715.
[23] Chen, Q. W.; Li, X. G.; Zhang, Y. H.; Qian, Y. T. Adv. Mater. 2002, 14, 134.
[24] Bao, C. L.; Song, L.; Xing, W. Y.; Yuan, B. H.; Wilkie, C. A.; Huang, J. L.; Guo, Y. Q.; Hu, Y. J. Mater. Chem. 2012, 22, 6088.
[25] Structural and Optical Properties of Porous Silicon Nanostructures, Eds.: Amato, G.; Delerue, C.; Von Bardeleben, H. J., Gordon and Breach Science Publishers, London, 1997.
[26] Kimmel, G. A.; Matthiesen, J.; Baer, M.; Mundy, C. J.; Petrik, N. G.; Smith, R. S.; Dohnalek, Z.; Kay, B. D. J. Am. Chem. Soc. 2009, 131, 12838.
[27] Chandra, V.; Park, J.; Chun, Y.; Lee, J. W.; Hwang, I. C.; Kim, K. S. ACS nano 2010, 4, 3979.
[28] Yu, Q. K.; Jauregui, L. A.; Wu, W.; Colby, R.; Tian, J.; Su, Z.; Cao, H.; Liu, Z.; Pandey, D.; Wei, D.; Chung, T. F.; Peng, P.; Guisinger, N. P.; Stach, E. A.; Bao, J.; Pei, S. S.; Chen, Y. P. Nat. Mater. 2011, 10, 443.
[29] Ferrari, A. C.; Robertson, J. Phys. Rev. B 2000, 61, 14095.
[30] Szabo, T.; Szabo, T.; Berkesi, O.; Forgo, P.; Josepovits, K.; Sanakis, Y.; Petridis, D.; Dekany, I. Chem. Mater. 2006, 18, 2740.
[31] Scholz, W.; Boehm, H. P. Z. Anorg. Allg. Chem. 1969, 369, 327.
/
〈 |
|
〉 |