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2014 , Vol. 72 >Issue 2: 185 - 200

DOI: https://doi.org/10.6023/A13080857

综述

石墨烯/碳纳米管复合材料的制备及应用进展

  • 赵冬梅 ,
  • 李振伟 ,
  • 刘领弟 ,
  • 张艳红 ,
  • 任德财 ,
  • 李坚
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  • a 东北林业大学生物材料科学与工程教育部重点实验室 哈尔滨 150040;
    b 黑龙江东方学院食品与环境工程学部 哈尔滨 150086;
    c 黑龙江大学功能无机材料化学教育部重点实验室 哈尔滨 150080

收稿日期: 2013-08-15

  网络出版日期: 2013-11-03

基金资助

项目受国家自然科学基金（No. 31270590）；中国博士后基金（No. 2013M531008）和黑龙江省教育厅项目（No. 12531521）资助.

收起

Progress of Preparation and Application of Graphene/Carbon Nanotube Composite Materials

  • Zhao Dongmei ,
  • Li Zhenwei ,
  • Liu Lingdi ,
  • Zhang Yanhong ,
  • Ren Decai ,
  • Li Jian
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  • a Key Laboratory of Bio-Based Material Science and Technology, Ministry of Education, Northeast Forest University, Harbin 150040;
    b Food and Environment Engineering Department, Heilongjiang East University, Harbin 150086;
    c Key Laboratory of Functional Inorganic Material Chemistry, Heilongjiang University, Harbin 150080

Received date: 2013-08-15

  Online published: 2013-11-03

Supported by

Project supported by the National Natural Science Foundation of China (No. 31270590), Postdoctoral Science Foundation Projects of China (No. 2013M531008) and Heilongjiang Provincial Department of Education Project (No. 12531521).

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摘要

石墨烯和碳纳米管都是纳米尺寸的碳材料，具有极大的比表面积、良好的导电性以及优秀的机械性能等特性. 选择合适的方法制备出石墨烯/碳纳米管复合材料，它们之间可以产生一种协同效应，使其各种物理化学性能得到增强，因而这种复合材料在很多领域有着极大的应用前景. 以石墨烯/碳纳米管复合材料为综述对象，详细地介绍了它的制备、掺杂和应用等方面的进展，同时也对其发展前景进行了展望. 这种复合材料不仅被成功地应用在电容器、光电器件、储能电池、电化学传感器和其它领域，而且也会在这些领域内深化并向其它领域延伸.

关键词： 石墨烯; 碳纳米管; 复合材料; 制备; 应用

本文引用格式

赵冬梅 , 李振伟 , 刘领弟 , 张艳红 , 任德财 , 李坚 . 石墨烯/碳纳米管复合材料的制备及应用进展[J]. 化学学报, 2014 , 72(2) : 185 -200 . DOI: 10.6023/A13080857

Abstract

Graphene and carbon nanotubes are nanometer-sized carbon materials with the characteristics of the great specific surface area, good electrical conductivity and excellent mechanical properties. Selecting appropriate methods to prepare graphene/carbon nanotube composites can generate a synergistic effect between them with many physical and chemical properties enhanced, and these composites have a great future in many areas. In this paper, some kinds of preparation methods about graphene/carbon nanotube composites were described in detail, such as chemical vapor deposition, layer by layer deposition, electrophoretic deposition, vacuum filtration, coating membrane and in situ chemical reduction method. The advantages and disadvantages of these methods were compared as table format. To further enhance the functions, the graphene/carbon nanotube composites were doped with other materials such as polymer materials, nanoparticles, metal oxide to achieve the purpose of modification. Some researchers proposed theoretical computer model design for some special composites structures such as three-dimensional columnar structure and spiral structure to improve the performance of composites. Meanwhile, the applications of composites in supercapacitor, a photoelectric conversion device, energy storage batteries, electrochemical sensors and other fields were discussed in detail. These applications fully proved that composites had a brighter future than pure graphene or carbon nanotube. In addition, the developments of composites are prospected. Preparations of grapheme/carbon nanotube composites are maturing, but a variety of methods have their drawbacks and shortcomings, to get preparation method with easy control operation, low production costs, high raw material utilization, good product quality needs further research and exploration. Preparations of the highly oriented columnar structures between the layers of graphene and carbon nanotube and three-dimensional structure with graphene helicaly inserted or wrapped carbon nanotubes still remain in the computer model. In the near future the studies of the composites will be deepen and extended to develop new fields.

Key words： graphene; carbon nanotube; composite; preparation; application

参考文献

[1] Rao, C. N. R.; Sood, A. K.; Subrahmanyam, K. S.; Govindaraj, A. Angew. Chem., Int. Ed. 2009, 48, 7752.

[2] Worsley, M. A.; Pauzauskie, P. J.; Olson, T. Y.; Biener, J.; Satcher, J. H., Jr.; Baumann, T. F. J. Am. Chem. Soc. 2010, 132, 14067.

[3] Guo, W. H.; Liu, C.; Sun, X. M.; Yang, Z. B.; Kia, H. G.; Peng, H. S. J. Mater. Chem. 2012, 22, 903.

[4] Varshney, V.; Patnaik, S. S.; Roy, A. K.; Froudakis, G.; Farmer, B. L. ACS Nano 2010, 4, 1153.

[5] Tung, V. C.; Chen, L. M.; Allen, M. J.; Wassei, J. K.; Nelson, K.; Kaner, R. B.; Yang, Y. Nano Lett. 2009, 9, 1949.

[6] Yoo, E.; Kim, J.; Hosono, E.; Zhou, H. S.; Kudo, T.; Honma, I.; Nano Lett. 2008, 8, 2277.

[7] Fan, Z. J.; Yan, J.; Zhi, L. J.; Zhang, Q.; Wei, T.; Feng, J.; Zhang, M. L.; Qian, W. Z.; Wei, F. Adv. Mater. 2010, 22, 3723.

[8] Yu, D. S.; Dai, L. M. J. Phys. Chem. Lett. 2009, 1, 467.

[9] Peng, L. W.; Feng, Y. Y.; Lv, P.; Lei, D.; Shen, Y. T.; Li, Y.; Feng, W. J. Phys. Chem. C 2012, 116, 4970.

[10] Lee, D. H.; Lee, J. A.; Lee, W. J.; Choi, D. S.; Lee, W. J.; Kim, S. O. J. Phys. Chem. C 2010, 114, 21184.

[11] Choi, H.; Kim, H.; Hwang, S.; Kang, M.; Jung, D. W.; Jeon, M. Scripta Materialia 2011, 64, 601.

[12] Li, X.; Zhu, G. X.; Xu, Z. Thin Solid Films 2012, 520, 1959.

[13] Hong, S. W.; Du, F.; Lan, W.; Kim, S.; Kim, H. S.; Rogers, J. A. Adv. Mater. 2011, 23, 3821.

[14] Nguyen, D. D.; Tai, N. H.; Chen, S. Y.; Chueh, Y. L. Nanoscale 2012, 4, 632.

[15] Chen, S. Q.; Chen, P.; Wang, Y. Nanoscale 2011, 3, 4323.

[16] Kim, U. J.; Lee, I. H.; Bae, J. J.; Lee, S.; Han, G. H.; Chae, S. J.; Günes, F.; Choi, J. H.; Baik, C. W.; Kim, S. I.; Kim, J. M.; Lee, Y. H. Adv. Mater. 2011, 23, 3809.

[17] Li, C. Y.; Li, Z.; Zhu, H. W.; Wang, K. L.; Wei, J. Q.; Li, X.; Sun, P. Z.; Zhang, H.; Wu, D. H. J. Phys. Chem. C 2010, 114, 14008.

[18] Dong, X. C.; Li, B.; Wei, A.; Cao, X. H.; Chan-Park, M. B.; Zhang, H.; Li, L. J.; Huang, W.; Chen, P. Carbon 2011, 49, 2944.

[19] Zhu, X.; Ning, G. Q.; Fan, Z. J.; Gao, J. S.; Xu, C. M.; Qian, W. Z.; Wei, F. Carbon 2012, 50, 2764.

[20] Lee, D. H.; Kim, J. E.; Han, T. H.; Hwang, J. W.; Jeon, S.; Choi, S. Y.; Hong, S. H.; Lee, W. J.; Ruoff, R. S.; Kim, S. O. Adv. Mater. 2010, 22, 1247.

[21] Yu, K. H.; Lu, G. H.; Bo, Z.; Mao, S.; Chen, J. H. J. Phys. Chem. Lett. 2011, 2, 1556.

[22] Nagatsu, M.; Yoshida, T.; Mesko, M.; Ogino, A.; Matsuda, T.; Tanaka, T.; Tatsuoka, H.; Murakami, K. Carbon 2006, 44, 3336.

[23] Hong, T. K.; Lee, D. W.; Choi, H. J.; Shin, H. S.; Kim, B. S. ACS Nano 2010, 4, 3861.

[24] Byon, H. R.; Lee, S. W.; Chen, S.; Hammond, P. T.; Horn, Y. S. Carbon 2011, 49, 457.

[25] Hong, J.; Kang, S. W. Colloids Surf. A: Physicochem. Eng. Aspects 2011, 374, 54.

[26] Kim, Y. K.; Min, D. H. Langmuir 2009, 25, 11302.

[27] Lee, J.; Kim, Y. K.; Min, D. H. J. Am. Chem. Soc. 2010, 132, 14714.

[28] Su, Y.; Zhitomirsky, I. J. Colloid Interface Sci. 2013, 399, 46

[29] Wu, Z. S.; Pei, S. F.; Ren, W. C.; Tang, D. M.; Gao, T. L.; Liu, B.; Li, F.; Liu, C.; Cheng, H. M. Adv. Mater. 2009, 21, 1756.

[30] Bon, S. B.; Valentini, L. Kenny, J. M.; Peponi, L.; Verdejo, R.; Lopez-Manchado, M. A. Phys. Status Solidi A 2010, 207, 2461.

[31] Lu, T.; Pan, L. K.; Li, H. B.; Nie, C. Y.; Zhu, M. F.; Sun, Z. J. Electroanal. Chem. 2011, 661, 270.

[32] Seo, S. D.; Hwang, I. S.; Lee, S. H.; Shim, H. W.; Kim, D. W. Ceram. Int. 2012, 38, 3017.

[33] Ata, M. S.; Sun, Y.; Li, X.; Zhitomirsky, I. Colloids Surf. A: Physicochem. Eng. Aspects 2012, 398, 9.

[34] Zhu, G.; Pan, L. K.; Lu, T.; Xu, T.; Sun, Z. J. Mater. Chem. 2011, 21, 14869.

[35] Eda, G.; Fanchini, G.; Chhowalla, M. Nat. Nanotechnol. 2008, 3, 270.

[36] Wu, Z. C.; Chen, Z. H.; Du, X.; Logan, J. M.; Sippel, J.; Nikolou, M.; Kamaras, K.; Reynolds, J. R.; Tanner, D. B.; Hebard, A. F.; Rinzler, A. G. Science 2004, 305, 1273.

[37] Hu, L.; Hecht, D. S.; Gruner, G. Nano Lett. 2004, 4, 2513.

[38] Unalan, H. E.; Fanchini, G.; Kanwal, A.; Du Pasquier. A.; Chhowalla, M. Nano Lett. 2006, 6, 677.

[39] Kim, D. H.; Yun, Y. S.; Bak, H.; Cho, S. Y.; Jin, H. J. Curr. Appl. Phys. 2011, 11, 376.

[40] Khan, U.; O'Connor, I.; Gun'ko, Y. K.; Coleman, J. N. Carbon 2010, 48, 2825.

[41] Furtado, C. A.; Kim, U. J.; Gutierrez, H. R.; Pan, L.; Dickey, E. C.; Eklund, P. C. J. Am. Chem. Soc. 2004, 126, 6095.

[42] Giordani, S.; Bergin, S. D.; Nicolosi, V.; Lebedkin, S.; Kappes, M. M.; Blau, W. J.; Coleman, J. N. J. Phys. Chem. B 2006, 110, 15708.

[43] Landi, B. J.; Ruf, H. J.; Worman, J. J.; Raffaelle, R. P. J. Phys. Chem. B 2004, 108, 17089.

[44] Bergin, S. D.; Nicolosi, V.; Streich, P. V.; Giordani, S.; Sun, Z.; Windle, A. H.; Ryan, P.; Niraj, N. P. P.; Wang, Z. T. T.; Carpenter, L.; Blau, W. J.; Boland, J. J.; Hamilton, J. P.; Coleman, J. N. Adv. Mater. 2008, 20, 1876.

[45] Hernandez, Y.; Nicolosi, V.; Lotya, M.; Blighe, F. M.; Sun, Z. Y.; De, S.; Mcgovern, I. T.; Holland, B.; Byrne, M.; Gun'ko, Y. K.; Boland, J. J.; Niraj, P.; Duesberg, G.; Krishnamurthy, S.; Goodhue, R.; Hutchison, J.; Scardaci, V.; Ferrari, A. C.; Coleman, J. N. Nat. Nanotechnol. 2008, 3, 563.

[46] Tang, Y.; Gou, J. H. Mater. Lett. 2010, 64. 2513.

[47] King, P. J.; Khan, U.; Lotya, M.; De, S.; Coleman, J. N. ACS Nano 2010, 4, 4238.

[48] Qiu, L.; Yang, X. W.; Gou, X. L.; Yang, W. R.; Ma, Z. F.; Wallace, G. G.; Li, D. Chem. Eur. J. 2010, 16, 10653.

[49] Zhang, C.; Ren, L. L.; Wang, X. Y.; Liu, T. X. J. Phys. Chem. C 2010, 114, 11435.

[50] Tian, L. L.; Meziani, M. J.; Lu, F. S.; Kong, C. Y.; Cao, L.; Thorne, T. J.; Sun, Y. P. ACS Appl. Mater. Interfaces 2010, 2, 3217.

[51] Lu, X. J.; Dou, H.; Gao, B.; Yuan, C. Z.; Yang, S. D.; Hao, L.; Shen, L. F.; Zhang, X. G. Electrochim. Acta 2011, 56, 5115.

[52] Dong, X. C.; Xing, G. C.; Chan-Park, M. B.; Shi, W. H.; Xiao, N.; Wang, J.; Yan, Q. Y.; Sum, T. C.; Huang, W.; Chen, P. Carbon 2011, 49, 5071.

[53] Jang, W. S.; Chae, S. S.; Lee, S. J.; Song, K. M.; Baik, H. K. Carbon 2012, 50, 943.

[54] Kim, J.; Tung, V. C.; Huang, J. X. Adv. Energy Mater. 2011, 1, 1052.

[55] Yang, S. Y.; Chang, K. H.; Tien, H. W.; Lee, Y. F.; Li, S. M.; Wang, Y. S.; Wang, J. Y.; Ma, C. C. M.; Hu, C. C. J. Mater. Chem. 2011, 21, 2374.

[56] Woo, S.; Kim, Y. R.; Chung, T. D.; Piao, Y. Z.; Kim, H. Electrochim. Acta 2012, 59, 509.

[57] Hu, F. X.; Chen, S. H.; Wang, C. Y.; Ruo, Y. D. H.; Wang, C. Anal. Chim. Acta 2012, 724, 40.

[58] Su, Q.; Liang, Y. Y.; Feng, X. L.; Mullen, K. Chem. Commun. 2010, 46, 8279.

[59] Kim, Y. K.; Min, D. H. Langmuir 2009, 25, 11302.

[60] Lee, J.; Kim, Y. K.; Min, D. H. J. Am. Chem. Soc. 2010, 132, 14714

[61] Vinayan, B. P.; Nagar, R.; Raman, V.; Rajalakshmi, N.; Dhathathreyan, K. S.; Ramaprabhu, S. J. Mater. Chem. 2012, 22, 9949.

[62] Tkalya, E. E.; Ghislandi, M.; With, G. D.; Koning, C. E. Curr. Opin. Colloid Interface Sci. 2012, 17, 225.

[63] Wu, Y. P.; Zhang, T. F.; Zhang, F.; Wang, Y.; Ma, Y. F.; Huang, Y.; Liu, Y. Y.; Chen, Y. S. Nano Energy 2012, 1, 820.

[64] Shao, J. J.; Lv, W.; Guo, Q. G.; Zhang, C.; Xu, Q.; Yang, Q. H. Kang, F.Y. Chem. Commun. 2012, 48, 3706.

[65] Chen, X.; Zhu, J. E.; Xi, Q.; Yang, W. S. Sens. Actuators, B 2012, 161, 648.

[66] Battumur, T.; Mujawar, S. H.; Truong, Q. T.; Ambade, S. B.; Lee, D. S.; Lee, W.; Han, S. H.; Lee, S. H. Curr. Appl. Phys. 2012, 12, 49.

[67] Liu, S.; Liu, X. H.; Li, Z. P.; Yang, S. R.; Wang, J. Q. New J. Chem. 2011, 35, 369.

[68] Feng, X. M.; Li, R. M.; Ma, Y. W.; Chen, R. F.; Shi, N. E.; Fan, Q. L.; Huang, W. Adv. Funct. Mater. 2011, 21, 2989.

[69] Gupta, V.; Miura, N. Electrochim. Acta 2006, 52, 1721.

[70] Zhou, Y.; Qin, Z .Y.; Li, L.; Zhang, Y.; Wei, Y. L.; Wang, L. F.; Zhu, M. F. Electrochim. Acta 2010, 55, 3904.

[71] Lu, X. J.; Dou, H.; Yang, S. D.; Hao, L.; Zhang, L. J.; Shen, L. F.; Zhang, F.; Zhang, X. G. Electrochim. Acta 2011, 56, 9224.

[72] Yan, J.; Wei, T.; Fan, Z. J.; Qian, W. Z.; Zhang, M. L.; Shen, X. D.; Wei, F. J. Power Sources 2010, 195, 3041.

[73] Ning, G. Q.; Li, T. Y.; Yan, J.; Xu, C. G.; Wei, T.; Fan, Z. J. Carbon 2013, 54, 241.

[74] Zheng, Z. X.; Wang, Z. H.; Feng, Q. L.; Zhang, F. Y.; Du, Y. L.; Wang, C. M. Mater. Chem. Phys. 2013, 138, 350.

[75] Lu, X. J.; Dou, H.; Yuan, C. Z.; Yang, S. D.; Hao, L.; Zhang, F.; Shen, L. F.; Zhang, L. J.; Zhang, X. G. J. Power Sources 2012, 197, 319.

[76] Ding, B.; Lu, X. J.; Yuan, C. Z.; Yang, S. D.; Han, Y. Q.; Zhang, X. G.; Che, Q. Electrochim. Acta 2012, 62, 132.

[77] Tung, V. C.; King, J.; Huang, J. X. Adv. Energy Mater. 2012, 2, 299.

[78] Saleh, M. H. A.; Sundararaj, U. Carbon 2009, 47, 2.

[79] Coleman, J. N.; Khan, U.; Blau, W. J.; Gun'ko, Y. K. Carbon 2006, 44, 1624.

[80] Qiu, L. B.; Sun, X. M.; Yang, Z. B.; Guo, W. H.; Peng, H. S. Acta Chim. Sinica 2012, 70, 1523. (丘龙斌, 孙雪梅, 仰志斌, 郭文瀚, 彭慧胜, 化学学报, 2012, 70, 1523.)

[81] Yang, D.; Hu, J. H.; Wang, C. C. Carbon 2006, 44, 3161.

[82] Yang, S. Y.; Ma, C. C. M.; Teng, C. C.; Huang, Y. W.; Liao, S. H.; Huang, Y. L.; Tien, H. W.; Lee, T. M.; Chiou, K. C. Carbon 2010, 48, 592.

[83] Zhang, Z. N.; Zhang, J.; Chen, P.; Zhang, B. Q.; He, J. S.; Hu, G. H. Carbon 2006, 44, 692.

[84] Ramanathan, T.; Abdala, A. A.; Stankovich, S.; Dikin, D. A.; Alonso, M. H.; Piner, R. D.; Adamson, D. H.; Schniepp, H. C.; Chen, X.; Ruoff, R. S.; Nguyen, S. T.; Aksay, I. A.; Prud'homme, R. K.; Brinson, L. C. Nat. Nanotechnol. 2008, 3, 327.

[85] Rafiee, M. A.; Rafiee, J.; Wang, Z.; Song, H. H.; Yu, Z. Z.; Koratkar, N. ACS Nano 2009, 3, 3884.

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