胆酸手性化氧化石墨烯杂化材料的制备及性能研究
收稿日期: 2014-08-28
网络出版日期: 2014-10-17
基金资助
项目受国家自然科学基金(Nos. 21274008, 21174010)、国家自然科学基金-创新研究群体科学基金(No. 51221002)和高等学校博士学科点专项科研基金(SRFDP No. 20120010130002)资助.
Cholic Acid/Graphene Oxide Chiral Hybrid Material: Preparation and Characterizations
Received date: 2014-08-28
Online published: 2014-10-17
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21274008, 21174010), the Funds for Creative Research Groups of China (No. 51221002) and the Specialized Research Fund for the Doctoral Program of Higher Education (SRFDP No. 20120010130002).
黄骅隽 , 任重磊 , 陈宇 , 杨万泰 , 邓建平 . 胆酸手性化氧化石墨烯杂化材料的制备及性能研究[J]. 化学学报, 2014 , 72(11) : 1169 -1174 . DOI: 10.6023/A14080614
The importance of chiral science and chiral materials has been increasingly highlighted. Meanwhile, graphene oxide (GO) and the derivatives are emerging materials with remarkable electronic, mechanical, and thermal properties. The present study intends to chirally functionalize oxide graphene (GO) by using a biomass cholic acid (CA), by which to establish a novel type of chiral hybrid materials. Based on expandable graphite powder, slightly modified Hummers method was adopted to prepare GO, on which 3-azidopropyltrimethoxysilane (APTMS) as N3 moieties were covalently attached by taking advantage of the reaction between the alkoxy groups of APTMS and the hydroxyl and epoxide groups of GO sheets, providing GO/APTMS. Alkynylated CA was prepared by a reaction of CA and propargylamine in the presence of isobutyl chloroformate and 4-methylmorpholine taken, according to our earlier method. Then, the solution was dried over anhydrous MgSO4, filtered, concentrated, and then purified by recrystallization twice from THF/hexane. Furthermore, the product was structurally identified by FT-IR and 1H NMR. Subsequently, alkynylated CA was grafted onto the surface of GO sheets through a "click" reaction between the azido groups on GO and the ethynyl groups in the alkynylated CA to produce chirally functionalized GO. The reaction was accomplished under a nitrogen atmosphere with addition of dry DMF, GO/APTMS, Alkynylated CA, CuBr, and PMDETA at room temperature for 48 h with magnetic stirring. Then the product was obtained by centrifugation at 18000 r/min for 30 min and further cleaned for three cycles by washing with DMF under sonication and centrifugation. Finally, the resulting chiral GO hybrid was dried under vacuum overnight and subjected to characterizations including FT-IR, XRD, XPS, Raman, TG, AFM, HRTEM, CD and UV. The characterizations in combination identified the success in preparing the target chiral hybrid material.
Key words： chiral materials; graphene oxide; cholic acid; click reaction
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