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2015 , Vol. 73 >Issue 1: 9 - 22

DOI: https://doi.org/10.6023/A14100716

综述

高效蓝光有机电致磷光主体材料的研究进展

  • 王芳芳 ,
  • 陶友田 ,
  • 黄维
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  • a 江苏省柔性电子重点实验室 南京工业大学先进材料研究院 南京 210009;
    b 内蒙古大学化学化工学院 呼和浩特 010021

收稿日期: 2014-10-16

  网络出版日期: 2014-11-28

基金资助

项目受青年973计划(No. 2014CB648300)、国家自然科学基金(No. 61474062)及江苏省自然科学基金青年项目(No. BK20130919)资助.

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Recent Progress of Host Materials for Highly Efficient Blue Phosphorescent OLEDs

  • Wang Fangfang ,
  • Tao Youtian ,
  • Huang Wei
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  • a Key Laboratory of Flexible Electronics, Institute of Advanced Materials, Nanjing Tech University, Nanjing 210009;
    b College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021

Received date: 2014-10-16

  Online published: 2014-11-28

Supported by

Project supported by the Youth Project 973 (No. 2014CB648300), the National Natural Science Foundation of China (No. 61474062) and the Natural Science Foundation of Jiangsu Province Youth Project (No. BK20130919).

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摘要

磷光有机发光二极管(PHOLEDs)相对于传统的荧光有机电致发光具有更高的量子效率, 在平板显示和固态照明方面有极大的应用前景. 本工作将近几年来外量子效率高于20%的蓝光PHOLEDs中小分子主体材料进行总结, 并按空穴传输型、电子传输型和双极传输型主体材料分类, 重点介绍这些材料的分子结构、三线态能级、HOMO/LUMO能级、热稳定性、形态稳定性以及作为蓝光PHOLEDs主体材料的器件性能, 以期对主体材料的研究及OLED产业化提供参考价值.

关键词： 有机电致发光; 磷光; 蓝光; 外量子效率; 主体

本文引用格式

王芳芳 , 陶友田 , 黄维 . 高效蓝光有机电致磷光主体材料的研究进展[J]. 化学学报, 2015 , 73(1) : 9 -22 . DOI: 10.6023/A14100716

Abstract

Phosphorescent organic light-emitting diodes (PHOLEDs) show a bright future for flat-panel displays and solid- state lighting due to higher quantum efficiencies compared with traditional fluorescent OLEDs. This review focuses on small-molecular organic host materials for blue PHOLEDs with external quantum efficiency higher than 20%. Hole transport-type, electron transport-type and bipolar transport hosts are introduced according to their charge transporting properties. Their molecular structures and physical properties such as triplet energy, HOMO/LUMO energy levels and thermal stabilities, as well as device performances of host materials for blue and deep-blue PHOLEDs are comprehensively demonstrated. It is expected to provide reference value for the exploitation of new organic host materials and the commercialization of OLEDs.

Key words： organic electroluminescence; phosphorescence; blue; external quantum efficiency; host

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