氮自由基化学新进展:光催化N-H键活化途径
收稿日期: 2017-08-23
网络出版日期: 2017-09-29
基金资助
项目受国家自然科学基金（Nos.21572140，21732005）和科技部重大新药专项（No.2017ZX09101005-009-002）资助.
Advances on Nitrogen-centered Radical Chemistry:A Photocatalytic N-H Bond Activation Approach
Received date: 2017-08-23
Online published: 2017-09-29
Supported by
Project supported by the National Natural Science Foundation of China (Nos. 21572140, 21732005) and the National Science and Technology Major Projects for "Major New Drugs Innovation and Development" (No. 2017ZX09101005-009-002).
宋颢 , 刘小宇 , 秦勇 . 氮自由基化学新进展:光催化N-H键活化途径[J]. 化学学报, 2017 , 75(12) : 1137 -1149 . DOI: 10.6023/A17080384
Nitrogen-centered radicals are highly reactive intermediates, which provide new opportunities for designing new chemical reactions and preparing nitrogen-containing molecules. Direct generation of nitrogen-centered radicals via activation of N-H bonds under photocatalytic conditions has emerged as a green, efficient, and economical process, where significant progress has been made with methodology development in very recent years. In this paper, we highlight the important advances in this area that were reported since 2016.
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