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2020 , Vol. 78 >Issue 2: 114 - 124

DOI: https://doi.org/10.6023/A19100385

综述

二次电池用局部高浓度电解质的研究进展与展望

  • 于喆 ,
  • 张建军 ,
  • 刘亭亭 ,
  • 唐犇 ,
  • 杨晓燕 ,
  • 周新红 ,
  • 崔光磊
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  • a 中国科学院青岛生物能源与过程研究所 青岛市储能产业技术研究院 青岛 266101;
    b 青岛科技大学 化学与分子工程学院 青岛 266042
于喆,女,青岛科技大学化学与分子工程学院硕士,中国科学院青岛生物能源与过程研究所联合培养硕士生.主要从事锂硫电池电解质的研究;崔光磊,研究员,博士生导师,2005年于中国科学院化学所获得有机化学博士学位,2005年9月至2009年2月先后在德国马普协会高分子所和固态所从事博士后研究.2009年2月起于中科院青岛生物能源与过程所工作.2009年入选中国科学院“百人计划”(终期评估优秀),2009年获山东省自然科学杰出青年基金资助,2015年入选山东省“泰山学者特聘专家”,2016年获国家自然科学杰出青年基金资助.主要从事低成本高效能源储存与转换器件的研究,作为负责人和主要参与者承担国家自然科学杰出青年基金,国家973计划,863计划,国家自然科学基金面上项目,省部级及中科院先导专项,企业横向项目等多项科研项目.

收稿日期: 2019-10-25

  网络出版日期: 2020-01-21

基金资助

项目受国家自然科学基金（Nos.51703236，51625204）资助.

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Research Progress and Perspectives of Localized High-concentration Electrolytes for Secondary Batteries

  • Yu Zhe ,
  • Zhang Jianjun ,
  • Liu Tingting ,
  • Tang Ben ,
  • Yang Xiaoyan ,
  • Zhou Xinhong ,
  • Cui Guanglei
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  • a Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao Industrial Energy Storage Technology Institute, Qingdao 266101, China;
    b College of Chemistry and Molecular Engineering, Qingdao University of Science&Technology, Qingdao 266042, China

Received date: 2019-10-25

  Online published: 2020-01-21

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 51703236, 51625204).

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摘要

电解质作为二次电池离子传导的重要介质，对于提升二次电池循环稳定性能、安全性能等方面起着至关重要的作用.局部高浓度电解质是指在高浓度电解质中加入“稀释剂”，形成盐的局部高浓度状态，既能兼具高浓度电解质的优异特性，又具有低成本和优良润湿性的特点，应用前景非常广阔.近几年，局部高浓度电解质在阻燃锂金属电池、高电压锂电池、低温锂电池、锂硫电池和钠电池等多方面应用广泛，且展现出非常好的使用效果.本综述重点从局部高浓度电解质的功能性应用角度出发，详细阐述了局部高浓度电解质的类型、制备、作用机理及其在不同二次电池中的功能性应用进展和主要研究现状，文末还对局部高浓度电解质的未来可能发展趋势进行了分析与展望.

关键词： 局部高浓度电解质; 二次电池; 功能性应用

本文引用格式

于喆 , 张建军 , 刘亭亭 , 唐犇 , 杨晓燕 , 周新红 , 崔光磊 . 二次电池用局部高浓度电解质的研究进展与展望[J]. 化学学报, 2020 , 78(2) : 114 -124 . DOI: 10.6023/A19100385

Abstract

The electrolyte, which is an important medium of ion conduction for secondary batteries, plays a crucial role in improving the cycling performance and safety performance of secondary batteries. Localized high-concentration electrolytes, which are formed by adding "diluent" into high-concentration electrolyte, not only reserve the outstanding properties of high-concentration electrolytes but also possess low viscosity, excellent wettability and low cost, promising broad application prospect. Localized high-concentration electrolytes have already played a part in flame-retardant lithium battery, high-voltage lithium battery, low-temperature lithium battery, lithium sulfur battery and sodium battery. Herein, this paper mainly reviews the types and preparation of localized high-concentration electrolytes and their functional mechanism and research status in various secondary batteries. We discuss the challenges and future development of localized high-concentration electrolytes and have the outlook at the end of the paper.

Key words： localized high-concentration electrolyte; secondary battery; functional application

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