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2020 , Vol. 78 >Issue 4: 289 - 298

DOI: https://doi.org/10.6023/A20020027

研究展望

非共价作用在过渡金属催化的选择性碳氢键活化中的应用

  • 廖港 ,
  • 吴勇杰 ,
  • 史炳锋
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  • 浙江大学化学系 杭州 310027
廖港,博士后,2018年毕业于浙江大学,获理学博士学位,导师为史炳锋教授.同年在浙江大学化学系进行博士后研究工作.主要研究方向为过渡金属催化不对称碳氢键官能团化;吴勇杰,2017年在浙江科技学院获学士学位,现在在浙江大学史炳锋教授的指导下攻读博士学位.主要研究方向为过渡金属催化不对称碳氢键官能团化;史炳锋,博士,教授,独立课题组组长.2001年本科毕业于南开大学化学系,2006年博士毕业于中国科学院上海有机化学研究所,导师为俞飚研究员.2006～2007年在University of California,San Diego从事博士后研究,2007～2010年加入The Scripps Research Institute从事博士后研究,导师余金权教授.2010年4月加入浙江大学化学系,任独立课题组组长,博士生导师.独立工作以来,以通讯作者发表研究论文九十余篇,主要研究领域为过渡金属催化的惰性键活化及其在天然产物全合成中的应用.

收稿日期: 2020-02-08

  网络出版日期: 2020-03-12

基金资助

项目受国家自然科学基金（Nos.21901228，21772170）、中国博士后科学基金（No.2019M650135）、浙江省万人计划青年拔尖（No.ZJWR0108）和浙江省自然科学基金（No.LR17B020001）资助.

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Noncovalent Interaction in Transition Metal-Catalyzed Selective C-H Activation

  • Liao Gang ,
  • Wu Yong-Jie ,
  • Shi Bing-Feng
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  • Department of Chemistry, Zhejiang University, Hangzhou 310027

Received date: 2020-02-08

  Online published: 2020-03-12

Supported by

Project supported by the National Natural Science Foundation of China (Nos. 21901228, 21772170), the China Postdoctoral Science Foundation (No. 2019M650135), the Outstanding Young Talents of Zhejiang Province High-level Personnel of Special Support (No. ZJWR0108) and the Natural Science Foundation of Zhejiang Province (No. LR17B020001).

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摘要

过渡金属催化的碳氢键活化是合成有机化合物最有效的工具之一，基于底物本身官能团或者共价键连接的导向基策略是目前实现碳氢键选择性活化的主要手段.非共价作用在分子生物学、超分子化学、材料科学及药物研发中具有重要意义，近年来，非共价作用也被应用于过渡金属催化的惰性碳氢键的选择性活化.本文总结了非共价作用在选择性碳氢键活化领域的研究进展，并按照非共价键的作用类型，将其分为氢键作用、离子对作用、路易斯酸碱对作用和静电作用等，探讨了催化体系中心金属、配体和底物间相互作用力的模式，并展望了未来研究工作的方向.

关键词： 非共价键作用; 选择性; 碳氢键活化; 瞬态导向

本文引用格式

廖港 , 吴勇杰 , 史炳锋 . 非共价作用在过渡金属催化的选择性碳氢键活化中的应用[J]. 化学学报, 2020 , 78(4) : 289 -298 . DOI: 10.6023/A20020027

Abstract

Transition metal-catalyzed direct C-H functionalization is one of the most efficient and powerful tools for the rapid synthesis of organic molecules. The use of functional groups in the molecules or covalently attached coordinating groups as directing groups has been realized as a major strategy to control the selectivity. Noncovalent interactions are of great importance in the field of molecular biology, supramolecular chemistry, material science and drug discovery. More recently, the use of well-designed ligands to enable the site-selective C-H functionalization via noncovalent interactions has emerged as a highly promising yet relatively less explored strategy. In this perspective, recent advances in this cutting-edge area are summarized. The perspective was classified into four sections according to the type of noncovalent interactions, including hydrogen bonding, ion pair, Lewis acid-base interaction and electrostatic interaction. Emphasis is placed on the mode of noncovalent interactions among the transition metals, ligands and substrates. The limitation of current research and the prospect of future work will also be discussed. We anticipate that this strategy might become a promising complementary strategy to control the positional selectivity in C-H functionalization reactions.

Key words： noncovalent interaction; selectivity; C—H activation; transient directing group

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