二维有机-无机杂化钙钛矿铁电材料的研究进展
 |
徐豪杰, 本科毕业于湖北大学材料科学与工程学院, 获学士学位. 目前就读于中国科学院福建物质结构研究所, 主要从事新型铁电材料的探索与性能研究. |
 |
韩世国, 2018年毕业于青岛大学物理科学学院, 获硕士学位. 目前在中国科学院福建物质结构研究所攻读博士学位. 当前的研究兴趣为新型光铁电体材料与光电应用探索. |
 |
孙志华, 中国科学院福建物质结构研究所研究员, 博士生导师. 主要从事极性光电功能材料的结构设计、化学合成与性能表征, 研究兴趣包括光敏铁电体、铁电半导体及材料的光电性能耦合与调控等. |
 |
罗军华, 中国科学院福建物质结构研究所研究员, 博士生导师, 上海科技大学特聘教授, 国家杰出青年基金获得者. 当前的主要研究方向为非中心对称结构的光电功能材料. |
收稿日期: 2020-08-18
网络出版日期: 2020-10-20
基金资助
国家自然科学基金(Nos. 21875251); 国家自然科学基金(21833010); 国家自然科学基金(21525104); 国家自然科学基金(21971238); 国家自然科学基金(21975258); 国家自然科学基金(61975207); 国家自然科学基金(21921001); 中科院基础前沿项目(ZDBS-LY-SLH024); 福建省自然科学基金(2018H0047); 中科院先导项目(XDB20010200)
Recent Advances of Two-dimensional Organic-Inorganic Hybrid Perovskite Ferroelectric Materials
Received date: 2020-08-18
Online published: 2020-10-20
Supported by
the National Natural Science Foundation of China(Nos. 21875251); the National Natural Science Foundation of China(21833010); the National Natural Science Foundation of China(21525104); the National Natural Science Foundation of China(21971238); the National Natural Science Foundation of China(21975258); the National Natural Science Foundation of China(61975207); the National Natural Science Foundation of China(21921001); the Key Research Program of Frontier Sciences of the Chinese Academy of Sciences(ZDBS-LY-SLH024); the Natural Science Foundation of Fujian Province(2018H0047); the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20010200)
铁电性通常是指电介质材料的自发极化取向随着外加电场发生变化的性能. 以自发极化为核心, 铁电材料表现出优异的介电响应、热释电性、压电性、电光效应和非线性光学效应等, 是一类具有广阔应用前景的功能材料. 近年来, 二维有机-无机杂化钙钛矿化合物在铁电研究领域崭露头角, 逐渐发展为铁电材料的重要组成部分. 此类材料具有独特的结构兼容性与可调控性, 能够实现多种功能的共存或耦合, 是发展新型多功能材料的理想体系. 本综述基于居里原理的对称性方法, 以铁电材料的结构相变为基础, 阐述了铁电体的晶体学对称性破缺现象. 具体结合二维有机-无机杂化钙钛矿铁电体的典型实例, 揭示材料铁电性能的结构来源及光电性能调控的潜在途径, 最后对该铁电材料体系的发展趋势和应用前景提出了展望.
徐豪杰 , 韩世国 , 孙志华 , 罗军华 . 二维有机-无机杂化钙钛矿铁电材料的研究进展[J]. 化学学报, 2021 , 79(1) : 23 -35 . DOI: 10.6023/A20080375
Ferroelectric materials, characterized by the reversible switching of spontaneous polarization by an applied electric field, exhibit excellent physical properties including dielectric response, pyroelectricity, piezoelectricity, electro-optics, and nonlinear optical effects, etc. All these physical properties have been widely used for diverse practical applications. In recent years, two-dimensional (2D) organic-inorganic hybrid perovskites have emerged as an important family of ferroelectrics. Benefitting from unique structural compatibility and tunability, this 2D class of ferroelectrics enable the coexistence and/or coupling of multiple functions, which become an ideal platform for the development of new multifunctional candidates. Based on the Curie symmetry principle, this work illuminates the crystallographic symmetry breaking and highlights the source of ferroelectricity in 2D hybrid perovskite ferroelectrics, as well as potential strategies to modulate their photoelectric properties. Finally, we propose the development trend and application prospects of these 2D hybrid perovskite ferroelectric materials.
| [1] | Sun, Z.-H.; Yi, X.-F.; Tao, K.-W.; Ji, C.-M.; Liu, X.-T.; Li, L.-N.; Han, S.-G.; Zheng, A.; Hong, M.-C.; Luo, J.-H. Angew. Chem., Int. Ed. 2018, 57, 9833. |
| [2] | Pandey, R.; Vats, G.; Yun, J.; Bowen, C.R.; Ho-Baillie, A.W.Y.; Seidel, J.; Butler, K.T.; Seok, S.I. Adv. Mater. 2019, 31, 1807376. |
| [3] | Ji, C.-M.; Wang, S.-S.; Li, L.-N.; Sun, Z.-H.; Hong, M.-C.; Luo, J.-H. Adv. Funct. Mater. 2018, 29, 1805038. |
| [4] | Fu, D.-W.; Cai, H.-L.; Liu, Y.; Ye, Q.; Zhang, W.; Zhang, Y.; Chen, X.-Y.; Giovannetti, G.; Capone, M.; Li, J.; Xiong, R.-G. Science 2013, 339, 425. |
| [5] | Ye, H.-Y.; Tang, Y.-Y.; Li, P.-F.; Liao, W.-Q.; Gao, J.-X.; Hua, X.-N.; Cai, H.; Shi, P.-P.; You, Y.-M.; Xiong, R.-G. Science 2018, 361, 151. |
| [6] | Kundys, B.; Lappas, A.; Viret, M.; Kapustianyk, V.; Rudyk, V.; Semak, S.; Simon, C.; Bakaimi, I. Phys. Rev. B 2010, 81, 224434. |
| [7] | Ye, H.-Y.; Zhou, Q.; Niu, X.; Liao, W.-Q.; Fu, D.-W.; Zhang, Y.; You, Y.-M.; Wang, J.; Chen, Z.-N.; Xiong, R.-G. J. Am. Chem. Soc. 2015, 137, 13148. |
| [8] | Li, X.; Zhang, T.-Y.; Wang, T.; Zhao, Y.-X. Acta Chim. Sinica 2019, 77, 1075 . (in Chinese) |
| [8] | 李鑫, 张太阳, 王甜, 赵一新, 化学学报, 2019, 77, 1075. |
| [9] | Zhang, X.-Y.; Li, L.-N.; Sun, Z.-H.; Luo, J.-H. Chem. Soc. Rev. 2019, 48, 517. |
| [10] | Chen, X.-Y.; Xie, J.-J.; Wang, W.; Yuan, H.-H.; Xu, D.; Zhang, T.; He, Y.-L.; Shen, H.-J. Acta Chim. Sinica 2019, 77, 9 . (in Chinese) |
| [10] | 陈薪羽, 解俊杰, 王炜, 袁慧慧, 许頔, 张焘, 何云龙, 沈沪江, 化学学报, 2019, 77, 9. |
| [11] | Zhang, H.-Y.; Tang, Y.-Y.; Shi, P.-P.; Xiong, R.-G. Acc. Chem. Res. 2019, 52, 1928. |
| [12] | Hang, T.; Zhang, W.; Ye, H.-Y.; Xiong, R.-G. Chem. Soc. Rev. 2011, 40, 3577. |
| [13] | Aizu, K. Phys. Rev. B 1970, 2, 754. |
| [14] | Aizu, K. J. Phys. Soc. Jpn. 1969, 27, 387. |
| [15] | Feng, J.-G.; Gong, C.; Gao, H.-F.; Wen, W.; Gong, Y.-J.; Jiang, X.-Y.; Zhang, B.; Wu, Y.-C.; Wu, Y.-S.; Fu, H.-B.; Jiang, L.; Zhang, X. Nat. Electron. 2018, 1, 404. |
| [16] | Wangyang, P.-H.; Gong, C.-H.; Rao, G.-F.; Hu, K.; Wang, X.-P.; Yan, C.-Y.; Dai, L.-P.; Wu, C.-Y.; Xiong, J. Adv. Opt. Mater. 2018, 6 . |
| [17] | Miao, J.-L.; Zhang, F.-J. J. Mater. Chem. C 2019, 7, 1741. |
| [18] | Ahn, J.; Ma, S.; Kim, J.Y.; Kyhm, J.; Yang, W.; Lim, J.A.; Kotov, N.A.; Moon, J. J. Am. Chem. Soc. 2020, 142, 4206. |
| [19] | Xiao, J.; Zhang, H.-L. Acta Phys.-Chim. Sin. 2016, 32, 1894 . (in Chinese) |
| [19] | 肖娟, 张浩力, 物理化学学报, 2016, 32, 1894. |
| [20] | Xia, M.-L.; Yuan, J.-H.; Luo, J.-J.; Pan, W.-C.; Wu, H.-D.; Chen, Q.; Xue, K.-H.; Miao, X.-S.; Niu, G.-D.; Tang, J. J. Mater. Chem. C 2020, 8, 3814. |
| [21] | Mao, L.; Stoumpos, C.C.; Kanatzidis, M.G. J. Am. Chem. Soc. 2019, 141, 1171. |
| [22] | Saparov, B.; Mitzi, D.B. Chem. Rev. 2016, 116, 4558. |
| [23] | Even, J.; Pedesseau, L.; Katan, C. ChemPhysChem 2014, 15, 3733. |
| [24] | Shi, P.-P.; Tang, Y.-Y.; Li, P.-F.; Liao, W.-Q.; Wang, Z.-X.; Ye, Q.; Xiong, R.-G. Chem. Soc. Rev. 2016, 45, 3811. |
| [25] | Liao, W.-Q.; Zhang, Y.; Hu, C.-L.; Mao, J.-G.; Ye, H.-Y.; Li, P.-F.; Huang, S.D.; Xiong, R.-G. Nat. Commun. 2015, 6, 7338. |
| [26] | Shi, P.-P.; Lu, S.-Q.; Song, X.-J.; Chen, X.-G.; Liao, W.-Q.; Li, P.-F.; Tang, Y.-Y.; Xiong, R.-G. J. Am. Chem. Soc. 2019, 141, 18334. |
| [27] | Wei, W.-J.; Li, C.; Li, L.-S.; Tang, Y.-Z.; Jiang, X.-X.; Lin, Z.-S. J. Mater. Chem. C 2019, 7, 11964. |
| [28] | Ye, H.-Y.; Liao, W.-Q.; Hu, C.-L.; Zhang, Y.; You, Y.-M.; Mao, J.-G.; Li, P.-F.; Xiong, R.-G. Adv. Mater. 2016, 28, 2579. |
| [29] | Sun, Z.-H.; Liu, X.-T.; Khan, T.; Ji, C.-M.; Asghar, M.A.; Zhao, S.-G.; Li, L.-N.; Hong, M.-C.; Luo, J.-H. Angew. Chem., Int. Ed. 2016, 55, 6545. |
| [30] | Hu, J.; Yan, L.; You, W. Adv. Mater. 2018, 30, 1802041. |
| [31] | Yang, C.-K.; Chen, W.-N.; Ding, Y.-T.; Wang, J.; Rao, Y.; Liao, W.-Q.; Tang, Y.-Y.; Li, P.-F.; Wang, Z.-X.; Xiong, R.-G. Adv. Mater. 2019, 31, 1808088. |
| [32] | Li, L.-N.; Liu, X.-T.; Li, Y.-B.; Xu, Z.-Y.; Wu, Z.-Y.; Han, S.-G.; Tao, K.-W.; Hong, M.-C.; Luo, J.-H.; Sun, Z.-H. J. Am. Chem. Soc. 2019, 141, 2623. |
| [33] | Li, L.-N.; Shang, X.-Y.; Wang, S.-S.; Dong, N.-N.; Ji, C.-M.; Chen, X.-Y.; Zhao, S.-G.; Wang, J.; Sun, Z.-H.; Hong, M.-C.; Luo, J.-H. J. Am. Chem. Soc. 2018, 140, 6806. |
| [34] | Lin, J.; Lai, M.; Dou, L.; Kley, C.S.; Chen, H.; Peng, F.; Sun, J.; Lu, D.; Hawks, S.A.; Xie, C.; Cui, F.; Alivisatos, A.P.; Limmer, D.T.; Yang, P. Nat. Mater. 2018, 17, 261. |
| [35] | Wu, Z.-Y.; Ji, C.-M.; Li, L.-N.; Kong, J.-T.; Sun, Z.-H.; Zhao, S.-G.; Wang, S.-S.; Hong, M.-C.; Luo, J.-H. Angew. Chem., Int. Ed. 2018, 57, 8140. |
| [36] | Stoumpos, C.C.; Cao, D.H.; Clark, D.J.; Young, J.; Rondinelli, J.M.; Jang, J.I.; Hupp, J.T.; Kanatzidis, M.G. Chem. Mater. 2016, 28, 2852. |
| [37] | Li, L.-N.; Sun, Z.-H.; Wang, P.; Hu, W.-D.; Wang, S.-S.; Ji, C.-M.; Hong, M.-C.; Luo, J.-H. Angew. Chem., Int. Ed. 2017, 56, 12150. |
| [38] | Liu, X.-T.; Wang, S.-S.; Long, P.-Q.; Li, L.-N.; Peng, Y.; Xu, Z.-Y.; Han, S.-G.; Sun, Z.-H.; Hong, M.-C.; Luo, J.-H. Angew. Chem., Int. Ed. 2019, 58, 14504. |
| [39] | Spanopoulos, I.; Hadar, I.; Ke, W.; Tu, Q.; Chen, M.; Tsai, H.; He, Y.; Shekhawat, G.; Dravid, V.P.; Wasielewski, M.R.; Mohite, A.D.; Stoumpos, C.C.; Kanatzidis, M.G. J. Am. Chem. Soc. 2019, 141, 5518. |
| [40] | Kieslich, G.; Sun, S.; Cheetham, A.K. Chem. Sci. 2014, 5, 4712. |
| [41] | Wang, S.-S.; Liu, X.-T.; Li, L.-N.; Ji, C.-M.; Sun, Z.-H.; Wu, Z.-Y.; Hong, M.-C.; Luo, J.-H. J. Am. Chem. Soc. 2019, 141, 7693. |
| [42] | Han, S.-G.; Liu, X.-T.; Liu, Y.; Xu, Z.-Y.; Li, Y.-B.; Hong, M.-C.; Luo, J.-H.; Sun, Z.-H. J. Am. Chem. Soc. 2019, 141, 12470. |
| [43] | Gao, Y.; Wei, Z.-T.; Yoo, P.; Shi, E.; Zeller, M.; Zhu, C.-H.; Liao, P.-L.; Dou, L.-T. J. Am. Chem. Soc. 2019, 141, 15577. |
| [44] | Li, L.-N.; Liu, X.-T.; He, C.; Wang, S.-S.; Ji, C.-M.; Zhang, X.-Y.; Sun, Z.-H.; Zhao, S.-G.; Hong, M.-C.; Luo, J.-H. J. Am. Chem. Soc. 2020, 142, 1159. |
| [45] | Mao, L.-L.; Ke, W.-J.; Pedesseau, L.; Wu, Y.-L.; Katan, C.; Even, J.; Wasielewski, M.R.; Stoumpos, C.C.; Kanatzidis, M.G. J. Am. Chem. Soc. 2018, 140, 3775. |
| [46] | Connor, B.A.; Leppert, L.; Smith, M.D.; Neaton, J.B.; Karunadasa, H.I. J. Am. Chem. Soc. 2018, 140, 5235. |
| [47] | Park, I.-H.; Zhang, Q.; Kwon, K.C.; Zhu, Z.; Yu, W.; Leng, K.; Giovanni, D.; Choi, H.S.; Abdelwahab, I.; Xu, Q.-H.; Sum, T.C.; Loh, K.P. J. Am. Chem. Soc. 2019, 141, 15972. |
| [48] | Guo, W.-Q.; Liu, X.-T.; Han, S.-G.; Liu, Y.; Xu, Z.-Y.; Hong, M.-C.; Luo, J.-H.; Sun, Z.-H. Angew. Chem., Int. Ed. 2020, 59, 2. |
| [49] | Sha, T.-T.; Xiong, Y.-A.; Pan, Q.; Chen, X.-G.; Song, X.-J.; Yao, J.; Miao, S.-R.; Jing, Z.-Y.; Feng, Z.-J.; You, Y.-M.; Xiong, R.-G. Adv. Mater. 2019, 31, 1901843. |
| [50] | Chen, X.-G.; Song, X.-J.; Zhang, Z.-X.; Li, P.-F.; Ge, J.-Z.; Tang, Y.-Y.; Gao, J.-X.; Zhang, W.-Y.; Fu, D.-W.; You, Y.-M.; Xiong, R.-G. J. Am. Chem. Soc. 2020, 142, 1077. |
| [51] | Zhang, H.-Y.; Song, X.-J.; Chen, X.-G.; Zhang, Z.-X.; You, Y.-M.; Tang, Y.-Y.; Xiong, R.-G. J. Am. Chem. Soc. 2020, 142, 4925. |
| [52] | Chen, X.-G.; Song, X.-J.; Zhang, Z.-X.; Zhang, H.-Y.; Pan, Q.; Yao, J.; You, Y.-M.; Xiong, R.-G. J. Am. Chem. Soc. 2020, 142,10212. |
| [53] | Wu, Z.-Y.; Liu, X.-T.; Ji, C.-M.; Li, L.-N.; Wang, S.-S.; Peng, Y.; Tao, K.-W.; Sun, Z.-H.; Hong, M.-C.; Luo, J.-H. J. Am. Chem. Soc. 2019, 141, 3812. |
| [54] | Wang, S.-S.; Li, L.-N.; Weng, W.; Ji, C.-M.; Liu, X.-T.; Sun, Z.-H.; Lin, W.-X.; Hong, M.-C.; Luo, J.-H. J. Am. Chem. Soc. 2019, 142, 55. |
| [55] | Ji, C.-M.; Wang, S.-S.; Wang, Y.-X.; Chen, H.-X.; Li, L.-N.; Sun, Z.-H.; Sui, Y.; Wang, S.-S.; Luo, J.-H. Adv. Funct. Mater. 2019, 30 . |
| [56] | Peng, Y.; Liu, X.-T.; Sun, Z.-H.; Ji, C.-M.; Li, L.-N.; Wu, Z.-Y.; Wang, S.-S.; Yao, Y.-P.; Hong, M.-C.; Luo, J.-H. Angew. Chem., Int. Ed. 2020, 59, 3933. |
| [57] | Shi, C.; Ye, L.; Gong, Z.-X.; Ma, J.-J.; Wang, Q.-W.; Jiang, J.-Y.; Hua, M.-M.; Wang, C.-F.; Yu, H.; Zhang, Y.; Ye, H.-Y. J. Am. Chem. Soc. 2019, 142, 545. |
| [58] | Zhang, W.-C.; Hong, M.-C.; Luo, J.-H. Angew. Chem., Int. Ed. 2020, 59, 9305. |
/
| 〈 |
|
〉 |
