环戊并二噻吩衍生物的合成及其应用
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魏颖, 南京邮电大学材料科学与工程学院副教授、硕士生导师. 2005至2009年就读于吉林化工学院, 获得学士学位. 2009至2014年就读于东北师范大学化学学院, 获得博士学位. 随后加入南京邮电大学信息材料与纳米技术研究院/材料科学与工程学院. 目前主要研究方向为有机/聚合物的合成及其性质. |
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解令海, 南京邮电大学信息材料与纳米技术研究院/材料科学与工程学院教授、博士生导师, 国家百千万人才工程人选, 享受国务院政府特殊津贴. 2000年和2003年分别获得东北师范大学学士学位和汕头大学硕士学位. 2003至2006年就读于复旦大学先进材料研究院, 获得博士学位. 他长期从事有机智能与第四代半导体研究, 涉及柔性电子、人工化学智能与智能化学、智能机器人化学家等未来领域的基础研究. |
收稿日期: 2021-05-07
网络出版日期: 2021-06-11
基金资助
国家自然科学基金(21774061); 国家自然科学基金(22071112); 江苏省高校自然科学研究面上项目(20KJB150038)
Synthesis and Application of Cyclopentadithiophene Derivatives
Received date: 2021-05-07
Online published: 2021-06-11
Supported by
National Natural Science Foundation of China(21774061); National Natural Science Foundation of China(22071112); Natural Science Research Project of Universities in Jiangsu Province(20KJB150038)
环戊并二噻吩衍生物作为一类具有刚性平面的类芴骨架结构的分子, 其光电材料衍生物由于具有带隙低、电导率高和良好的电荷传输性能等优点在塑料电子领域有着广泛的应用. 同时由于其易于进行结构修饰, 能够方便、快捷地引入各种功能基团, 可拓展合成多种衍生物. 依据环戊并二噻吩上噻吩S原子的位置不同, 可以将其分为6种构造异构体. 在这些构造异构体中, 目前关于4H-环戊[2,1-b:3,4-b']二噻吩衍生物的研究报道较多. 作者对4H-环戊[2,1-b:3,4-b']二噻吩衍生物的合成、性质及其在有机太阳能电池(OSCs)、有机场效应晶体管(OFETs)、有机发光二极管(OLEDs)等领域的研究进展进行了全面综述, 并对其有机半导体的格子化学进行了展望.
胡鑫明 , 钟春晓 , 李晓艳 , 贾雄 , 魏颖 , 解令海 . 环戊并二噻吩衍生物的合成及其应用[J]. 化学学报, 2021 , 79(8) : 953 -966 . DOI: 10.6023/A21050196
Cyclopentadithiophene (CPDT) derivatives, as a class of fluorene-like molecular building blocks that have a wide range of applications in the design of organic optoelectronic materials due to their easily molecular tailoring, electron-rich, low band gap, high electrical conductivity and good charge transport properties in the field of plastic electronics. At the same time, cyclopentadithiophene is easy to carry out structural modification, which can introduce various functional groups conveniently and quickly, and can expand a variety of derivatives. Cyclopentadithiophene can be divided into six structural isomers based on the position of the S atom on thiophene. Among these structural isomers, there are many reports on 4H-cyclopenta[2,1-b:3,4-b']dithiophene derivatives. In this article, we review mainly the synthesis and properties of 4H-cyclopenta[2,1-b:3,4-b']dithiophene derivatives and applications in organic solar cells (OSCs), organic field-effect transistors (OFETs). The research progress in organic light-emitting diodes (OLEDs) and other fields is also comprehensively summarized. The perspectives of the gridochemistry of CPDT-based organic semiconductors will be made finally.
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