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2023 , Vol. 81 >Issue 1: 84 - 99

DOI: https://doi.org/10.6023/A22100425

综述

三核过渡金属配合物在催化反应中的研究进展

  • 马雪璐 ,
  • 李蒙 ,
  • 雷鸣
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  • a 中国矿业大学(北京) 化学与环境工程学院 北京 100083
    b 闽江学院 福建省海洋传感功能材料重点实验室 福州 350108
    c 北京化工大学化工资源有效利用国家重点实验室 计算化学研究所 化学学院 北京 100029

马雪璐, 博士, 中国矿业大学(北京)化学与环境工程学院讲师, 硕士研究生导师. 2016年博士毕业于北京化工大学理学院(导师: 雷鸣教授); 同年进入清华大学化学系从事博士后研究工作(导师: 李隽教授). 2018年至今就职于中国矿业大学(北京)化学与环境工程学院, 主要研究方向为绿色催化反应体系的理论设计研究.

李蒙, 中国矿业大学(北京)2020级在读硕士研究生. 2015年获河北科技师范学院学士学位. 研究方向为均相催化剂的理论设计研究.

雷鸣, 北京化工大学化工资源有效利用国家重点实验室、计算化学研究所及化学学院物理化学系教授、博士生导师. 研究方向为计算催化化学. 在均相催化、多相催化催化机制、催化剂分子设计、理论计算化学及其交叉领域进行了探索性学术研究工作.

收稿日期: 2022-10-11

  网络出版日期: 2022-12-05

基金资助

项目受中央高校基本科研业务费(2022YQHH01); 福建省海洋传感功能材料重点实验室(闽江学院)开放课题(MJUKF-FMSM202202); 国家自然科学基金(21902182)

收起

Trinuclear Transition Metal Complexes in Catalytic Reactions

  • Xuelu Ma ,
  • Meng Li ,
  • Ming Lei
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  • a School of Chemical & Environmental Engineering, China University of Mining & Technology, Beijing 100083
    b Fujian Key Laboratory of Functional Marine Sensing Materials, Minjiang University, Fuzhou 350108
    c State Key Laboratory of Chemical Resource Engineering, Institute of Computational Chemistry, College of Chemistry, Beijing University of Chemical Technology, Beijing 100029
*E-mail: ;

Received date: 2022-10-11

  Online published: 2022-12-05

Supported by

Fundamental Research Funds for the Central Universities(2022YQHH01); Open Project Program of Fujian Key Laboratory of Functional Marine Sensing Materials(MJUKF-FMSM202202); National Natural Science Foundation of China(21902182)

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摘要

多核过渡金属配合物作为一类广泛应用的均相催化剂, 其设计灵感往往来自天然酶的多金属活性位点所发挥的重要作用. 目前, 三核金属配合物作为活化小分子的多金属催化剂受到了广泛的关注. 为深入理解三核过渡金属配合物在催化反应中作用特点, 对近年报道的代表性三核过渡金属配合物按金属中心进行分类, 并对配体环境形成特点及催化应用进行综述. 从金属中心出发, 讨论了三核过渡金属配合物的几何结构和电子特征; 从配体环境出发, 总结了关联三个独立的金属位点的配位环境特征; 在催化应用方面, 重点综述了三核过渡金属配合物在涉及特定化学键活化反应的催化作用机制, 最后对三核过渡金属配合物的催化应用前景进行展望.

关键词： 三核过渡金属配合物; 均相催化; 化学键活化; 协同作用

本文引用格式

马雪璐 , 李蒙 , 雷鸣 . 三核过渡金属配合物在催化反应中的研究进展[J]. 化学学报, 2023 , 81(1) : 84 -99 . DOI: 10.6023/A22100425

Abstract

Polynuclear transition metal complexes are widely used as homogeneous catalysts, and the polymetallic active sites of enzymes also play an important role in the mechanism of biochemical reactions under ambient conditions. As the efficient polymetallic catalysts for the activation of small molecules, trinuclear metal complexes have been attracted extensive attention. In order to understand the role of trinuclear transition metal complexes in catalytic reactions, we have classified the trinuclear transition metal complexes according to metal centers, and summarized the characteristics of their ligands, as well as their catalytic applications. Based on the metal centers, the geometric structure and electronic characteristics of the complexes are discussed. Based on the peripheral ligands, the characteristics of the coordination environment, which enable the aggregation of three independent metal sites, are highlighted. In terms of catalytic applications of trinuclear transition metal complexes, the catalytic mechanisms involving specific chemical bonds activation are focused on. Finally, we outlook the crucial potential application in this emerging field.

Key words： trinuclear transition metal complexes; homogeneous catalysis; chemical bond activation; synergy mechanism

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