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刘康, 2016年6月毕业于湖北大学化学化工学院, 获理学学士学位; 2021年12月毕业于中国科学院高能物理研究所, 获理学博士学位; 2022年1月至今中国科学院高能物理研究所博士后. 目前主要研究方向: 低价锕系化学. |
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郭燕, 博士, 讲师. 2008年获宁夏大学学士学位; 2012年获宁夏大学硕士学位; 2020年获西北大学博士学位; 2020年9月加入宁夏大学化学化工学院从事教学科研工作; 2022年2月至今在中国科学院高能物理研究所从事博士后研究. 目前主要研究方向: 低价金属配合物的合成及磁性研究. |
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于吉攀, 副研究员. 2008年获江苏师范大学学士学位; 2011年获南开大学硕士学位; 2014年获清华大学博士学位; 2014年7月至2016年7月清华大学化学系博士后; 2016年7月加入中国科学院高能物理研究所核能放射化学实验室. 目前主要研究方向: 锕系元素化学. |
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石伟群, 研究员, 国家杰出青年科学基金获得者, 长期致力于核燃料循环化学与锕系元素化学相关基础研究, 在JACS、Angew. Chem、Chem、CCS Chem.、Nat. Commun.、Adv. Mater.、Environ. Sci. Technol.等国际知名期刊发表SCI 论文300余篇, 成果被国内外同行广泛关注和引用, 文章总引1万余次, H因子55 (Google Scholar). 分别担任期刊《Chinese Chemical Letters》、《Journal of Nuclear Fuel Cycle and Waste Technology》和《Journal of Nuclear Science and Technology》的编委与国际顾问编委, 中文期刊《核化学与放射化学》编委. 现为中国化学会核化学与放射化学专业委员会委员、中国核学会锕系物理与化学分会副理事长、中国有色金属学会熔盐化学与技术专业委员会副主任委员、中国核学会核化工分会理事兼副秘书长. |
收稿日期: 2022-11-23
网络出版日期: 2023-01-28
基金资助
国家自然科学基金(22176191); 国家自然科学基金(21925603)
Research Progress of Actinide Single Molecule Magnets
Received date: 2022-11-23
Online published: 2023-01-28
Supported by
National Natural Science Foundation of China(22176191); National Natural Science Foundation of China(21925603)
刘康 , 郭燕 , 于吉攀 , 石伟群 . 锕系单分子磁体研究进展[J]. 化学学报, 2023 , 81(3) : 264 -274 . DOI: 10.6023/A22110471
Single molecule magnets is a kind of magnetic materials composed of a single molecule. Its magnetism stems from the magnetic moment of a single molecule. It is expected to be applied in ultra-high density storage, quantum computer, spintronics and other fields. Actinide single molecule magnets have attracted more and more attention due to the great spin-orbit coupling effect of actinides and large radial extension of 5f electrons, and demonstrate promise for exceeding the magnetism performance of transition metal and lanthanide complexes. However, the relaxation mechanism of actinide single molecule magnets and the factors of slow magnetic behavior remain unclear. In this review, the reported actinide single molecule magnets in the last ten years are summarized. It is found that the experimental values of blocking barrier are absolutely inconsistent with the theoretical values, which limited the development of actinide single molecule magnets to some extent. Finally, the future research directions of actinide single molecule magnets are prospected.
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