6,6″-二(2,6-二甲氧基苯)-三联吡啶及其衍生物金属配位自组装的研究进展
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王敏, 广州大学环境科学与工程学院环境工程专业在读硕士生. |
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蒋志龙, 广州大学大湾区环境研究院副教授, 主要的研究方向为超分子自组装及功能配合物, 参与国家自然科学基金面上项目3项, 主持贵州省科技厅科技创新项目1项, 广东省教育厅科技创新项目1项, 广州市市校联合基金1项, 目前以第一作者或者通讯作者身份在Nature Communication、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、iScience、Cell Reports Physical Science、Nano Research、Chem. Commun.、Inorg. Chem.等期刊上发表论文17篇, 授权中国发明专利6项. |
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王平山, 广州大学大湾区环境研究院教授, 中南大学化学化工学院特聘教授, 入选中组部海外高层次人才计划和湖南省“国家级领军人才”, 主持国家、国际环境署/环保部及美国科研项目20余项, 获省部级科技奖励3项, 目前研究领域主要集中在超分子化学、金属有机高分子能源材料和高分子环保材料, 在Science, Nat. Commun., J. Am. Chem. Soc., Angew. Chem. Int. Ed.等期刊发表学术论文100余篇, 授权国际和中国发明专利30余项, 在超大单分子的构筑策略研究领域有突出贡献, 相关成果在国内外具有重要的影响. |
收稿日期: 2023-12-19
网络出版日期: 2024-01-18
基金资助
国家自然科学基金(22101060); 国家自然科学基金(21971257); 广州市科技计划项目(202201020201); 广州市科技计划项目(SL2022A03J01050)
Research Progress on Metal-coordination-driven Self-assembly of 6,6"-Bis(2,6-dimethoxy-benzene)-terpyridine and Its Derivatives
Received date: 2023-12-19
Online published: 2024-01-18
Supported by
National Natural Science Foundation of China(22101060); National Natural Science Foundation of China(21971257); Science and Technology Planning Project of Guangzhou(202201020201); Science and Technology Planning Project of Guangzhou(SL2022A03J01050)
过去几年里, 6,6"-二(2,6-二甲氧基苯)-三联吡啶及其衍生物在多组分自组装过程中具有自识别能力强, 能够有效抑制副产物的生成等特点, 因此在精确构建多配体参与的金属配位超分子结构及功能研究方面具有独特优势. 这种新型互补型配体的应用不仅丰富了三联吡啶金属配位超分子结构的研究内容, 还展示了在发光材料、主客体化学、药物载体和限域催化等领域的广阔应用前景. 基于此, 本综述对基于6,6"-二(2,6-二甲氧基苯)-三联吡啶的衍生配体配位自组装研究中的最新进展进行了系统总结, 并简要探讨了此领域目前所面临的发展机遇及挑战.
王敏 , 陈帮塘 , 陈桥林 , 王俊 , 陈名钊 , 蒋志龙 , 王平山 . 6,6″-二(2,6-二甲氧基苯)-三联吡啶及其衍生物金属配位自组装的研究进展[J]. 化学学报, 2024 , 82(3) : 336 -347 . DOI: 10.6023/A23120538
In the past few decades, coordination-driven self-assembly of metal ions and organic ligands has been extensively applied in the construction of a variety of functional two-dimensional (2D) and three-dimensional (3D) structures. The majority of these structures are consisted of one type of ligand. Nevertheless, there have been sustained efforts dedicated to constructing heteroleptic assemblies using various strategic methods in order to increase the complexity and sophistication of nano-scale structures. Heteroleptic assemblies involve the use of multiple types of ligands, to assemble metal ions into more intricate structures. This approach allows for the incorporation of different ligand geometries, charge densities, and functional groups, leading to increased structural diversity and potential for new properties. To achieve heteroleptic assemblies, various strategic methods have been employed. One common approach is the use of different ligands with complementary binding properties, allowing for the controlled formation of targeted structures. In recent years, 6,6"-bis(2,6-dimethoxy-phenyl)- terpyridine and its derivatives have received considerable attention in the research of coordination-driven supramolecular self-assembly. These ligands exhibit strong self-recognition ability and effectively suppress the formation of by-products in multicomponent self-assembly processes, giving them unique advantages in the precise construction of metal-coordination supramolecular structures involving multiple ligands. A large number of 2D and 3D supramolecular structures formed by the coordination of 6,6"-bis(2,6-dimethoxy-phenyl)-terpyridine ligands and their derivatives with metal ions have been reported. The successful construction of these 2D and 3D topological structures has not only enriched the research of terpyridine metal-coordination supramolecular structures but also demonstrated significant research value and broad prospects in fields such as luminescent materials, host-guest chemistry, drug delivery systems, and confined catalysis. Based on this, this review systematically summarizes the latest progress in the self-assembly of derivative ligands based on 6,6"-bis(2,6-dimethoxy- phenyl)-terpyridine in terms of ligand synthesis, structure construction and property study, and briefly discusses the current development opportunities and challenges faced in this field.
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