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DOI: https://doi.org/10.6023/A26040102

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多孔芳香骨架光催化材料的合理设计与应用

  • 辛翠 ,
  • 邵京京 ,
  • 何禹萱 ,
  • 陶鑫
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  • a湖南警察学院 食药环及毒品检验技术湖南省普通高等学校重点实验室 长沙 410138;
    b东北师范大学化学学院 多酸与网格材料化学教育部重点实验室 长春 130024
辛翠,湖南警察学院刑事科学技术系讲师,主要研究方向为功能材料的合成及在法庭科学领域的应用。
邵京京,就读于东北师范大学化学学院,2023级无机化学硕士研究生,主要研究方向为面向光催化应用的多孔芳香骨架材料的设计与合成。
何禹萱,就读于东北师范大学化学学院,2023级无机化学硕士研究生,主要研究方向为面向光催化应用的多孔芳香骨架材料的设计与合成。
陶鑫,东北师范大学化学学院教授。2014年于吉林大学获理学博士学位。2014年至2019年期间,先后在中国科学院长春应用化学研究所及德国明斯特大学从事博士后研究。目前主要研究方向为面向能源与环境催化的新型多孔有机材料合成。

收稿日期: 2026-04-03

  网络出版日期: 2026-06-04

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Rational Design and Applications of Porous Aromatic Frameworks Photocatalytic Materials

  • Xin Cui ,
  • Jingjing Shao ,
  • Yuxuan He
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  • aInvestigation Department, Hunan Police Academy, Changsha 410138;
    bKey Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024

Received date: 2026-04-03

  Online published: 2026-06-04

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摘要

光催化技术因其绿色环保、可持续、反应条件温和及低成本易制备等特性,在大气污染物治理、水体环境净化、氢能源制备等能源转换、有机合成等诸多领域均展现出广阔应用前景与发展潜力。多孔芳香骨架（PAFs）是一类新兴的有机多孔材料。凭借分子层面可精准调控的拓扑结构、牢固稳定的共价化学键合作用、较高比表面积与孔隙率以及优异的化学稳定性和热稳定性等独特优势,已被广泛证实是极具研究价值的高效、稳定光催化材料。因此,合理构筑具备可调光学带隙、适宜能带结构和高效光生载流子分离与迁移能力的PAFs材料,并将其应用于光催化领域,对新型光催化材料的合理设计与性能革新具有重要意义。本综述系统总结了PAFs在光催化领域的最新研究进展,包括PAFs的结构设计策略、光催化机理、应用以及未来发展方向,旨在为设计高性能PAFs光催化剂提供理论指导和实践参考。

关键词： 光催化; 多孔芳香骨架; 应用进展

本文引用格式

辛翠 , 邵京京 , 何禹萱 , 陶鑫 . 多孔芳香骨架光催化材料的合理设计与应用[J]. 化学学报, 0 : 40102 -40102 . DOI: 10.6023/A26040102

Abstract

Photocatalytic technology, renowned for its environmental, friendliness, mild reaction conditions, low operational cost, and facile synthetic accessibility, has emerged as one of the most compelling green technologies in modern society. It exhibits promising prospects for practical applications across a broad spectrum of application fields, including atmospheric pollutant abatement, wastewater treatment, aquatic environmental remediation, clean hydrogen evolution, renewable energy conversion, organic synthesis, and green chemical transformation. By harnessing solar energy as the primary driving force, photocatalysis enables the efficient catalytic transformations, successfully achieving storage and conversion of solar energy into chemicals. This strategy is well aligned with the goals of carbon neutrality and sustainable social development. Porous Aromatic Frameworks (PAFs) represent an innovative category of organic porous materials with broad application prospects. They possess distinctive advantages including precisely tunable topological structures at the molecular level, robust stable covalent linkages, ultra-high specific surface area and favorable porosity, as well as excellent chemical and thermal stability under harsh environments. Meanwhile, PAFs incorporated with diverse photoactive units also exhibit superior light-harvesting capacity across a broad light spectrum, abundant exposed active sites and extended conjugated skeleton structures, thus serving as a promising platform for fabricating high-performance and long-term high-stability photocatalysts. Thus, rationally designing and constructing functional PAFs with adjustable bandgaps, regulated energy levels and efficient photogenerated charge carrier separation and migration, as well as extensively exploring their diverse photocatalytic applications, are of great theoretical and practical significance for linking the internal structure and photocatalytic performance of advanced porous organic semiconductor photocatalysts. This review systematically summarizes the latest research progress and representative achievements of PAFs in the field of photocatalysis, focusing on their molecular and structural design strategies, photocatalytic reaction mechanisms, diverse application scenarios, as well as existing challenges and future development directions. It aims to provide solid theoretical guidance and valuable practical references for the subsequent development and fabrication of high-performance PAF-based semiconductor photocatalysts.

Key words： photocatalysis; porous aromatic frameworks; application progress

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