Synthesis and Characterization of Polyacrylates Containing Trifluorovinyl Aryl Ether Side Group

doi:10.6023/A1107271

Acta Chimica Sinica ›› 2011, Vol. 69 ›› Issue (24): 2995-3001.DOI: 10.6023/A1107271 Previous Articles Next Articles

Full Papers

含有三氟乙烯基芳基醚侧基的聚丙烯酸酯的合成与表征

吕绪良*^,1, 王广银¹, 王可佳¹, 荣先辉², 贾其¹

(¹解放军理工大学工程兵工程学院南京 210007)
(²解放军理工大学科研部南京 210007)

投稿日期:2011-07-27 修回日期:2011-08-14 发布日期:2011-08-24
通讯作者: 吕绪良 E-mail:xllu1957@126.com

Synthesis and Characterization of Polyacrylates Containing Trifluorovinyl Aryl Ether Side Group

Lü Xuliang*^,1; Wang Guangyin¹; Wang Kejia¹; Rong Xianhui²; Jia Qi¹

(¹Engineering Institute of Corps of Engineer, PLA University of Science & Technology, Nanjing 210007)
(²Department of Scientific Research, PLA University of Science & Technology, Nanjing 210007)

Received:2011-07-27 Revised:2011-08-14 Published:2011-08-24

The introduction of trifluorovinyl aryl ether group into polyacrylate was studied. Firstly, a new acrylate monomer containing trifluorovinyl (TFVE) aryl ether side group was synthesized. Homopolymerization and random copolymerization of this monomer were conducted via atom transfer radical polymerization (ATRP) to get TFVE aryl ether-containing polyacrylates with narrow molecular weight distributions. A series of polyacrylates with different contents of TFVE aryl ether group were obtained by tuning the feeding ratios.

Key words: atom transfer radical polymerization, trifluorovinyl aryl ether, random copolymer

Cite this article

LV Xu-Liang, WANG Guang-Yin, WANG Ke-Jia, RONG Xian-Hui, JIA Qi. Synthesis and Characterization of Polyacrylates Containing Trifluorovinyl Aryl Ether Side Group[J]. Acta Chimica Sinica, 2011, 69(24): 2995-3001.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Lele Li, Yangyang Xiang, Huan Liu, Shuanhong Ma, Bin Li, Zhengfeng Ma, Qiangbing Wei, Bo Yu, Feng Zhou. Temperature-Responsive Nanofibrous Membranes Fabricated by Subsurface-Initiated Atom Transfer Radical Polymerization for Controllable Oil/Water Separation [J]. Acta Chimica Sinica, 2021, 79(3): 353-360.
[2]	Li Rongye, Khiman Mehul, Sheng Li, Sun Jing. pH/Solvent Tunable Hierarchical Nanostructures Assembled from an Amphiphilic Polypeptide-containing Triblock Copolymer [J]. Acta Chimica Sinica, 2020, 78(11): 1235-1239.
[3]	Yang Jing, Dong Jiabin, Ye Zhengde, Zhang Lei, Wang Yan, Gong Bolin. Preparation of P_DMAEMA Hydrophilic Interaction Chromatographic Stationary Phase by Atom Transfer Radical Polymerization and Its Chromatographic Properties [J]. Acta Chimica Sinica, 2012, 70(16): 1725-1730.
[4]	Zhang Wenjian, Fan Wei, Li Min, Hong Chunyan, Pan Caiyuan. Multi-responsive Hyperbranched Star Copolymer: Synthesis, Self-assembly and Controlled Release [J]. Acta Chimica Sinica, 2012, 70(16): 1690-1696.
[5]	Wang Shihai, Yang Nianfa, Yang Liwen, Gong Hang. Synthesis of Several Chiral Atom Transfer Radical Polymerization Initiators and Its Helix-sense-selective Initiating Function for ATRP [J]. Acta Chimica Sinica, 2012, 70(13): 1488-1495.
[6]	Wang Huaisong, Peng Jiangtao, Wei Jiping, Jiang An. Synthesis of Novel Chiral Stationary Phase Based on Atom Transfer Radical Polymerization and Click Chemistry [J]. Acta Chimica Sinica, 2012, 70(12): 1355-1361.
[7]	DANG Li, LIU Shou-Xin, YANG Xi, QI Xiao-Jun, WANG Hong-Mei, LV Hai-Yan, TIAN Rong. Synthesis and Micellization of Phosphorylcholine-Based pH-Responsive Triblock Copolymers [J]. Acta Chimica Sinica, 2011, 69(23): 2755-2761.
[8]	QI Xiao-Jun, LIU Shou-Xin, LIU Teng, DANG Li, YANG Xi, YU Wei-Na, WANG Hong-Mei. Synthesis and Characterization of Temperature- and pH-Sensitive P(HEMA-co-DEAEMA)-b-PDEAM-b-P(DEAEMA-co-HEMA) Block Copolymers [J]. Acta Chimica Sinica, 2011, 69(15): 1803-1810.
[9]	CHEN Jian-Fang, LING Ai-Hua, WANG Xia-Yu. Synthesis and Their Liquid Crystalline Behavior of Y-Type Miktoarm Star Mesogen-jacketed Liquid Crystalline Copolymer [J]. Acta Chimica Sinica, 2011, 69(08): 993-998.
[10]	FANG Yan, DI Guang-Qun, JIANG Bi-Biao, CHEN Jian-Hai. Low-Temperature Atom Transfer Radical Polymerization of Styrene: Diffusion-induced Acceleration [J]. Acta Chimica Sinica, 2011, 69(07): 853-862.
[11]	WANG E-Na, DUAN Shu-Jing, HE Xi-Wen, CHEN Lang-Xing, LI Wen-You, ZHANG Yu-Kui. Preparation of anStrong Anion-Exchange Ion-Exchange Chromatographic Support by Atom Transfer Radical Polymerization and Their Application in pProtein s Separation [J]. Acta Chimica Sinica, 2010, 68(23): 2421-2428.
[12]	ZHU Ya-Ming, ZHANG Yan, LIU Zi-Lu, LANG Mei-Dong. Controlled Synthesis and Properties of Triblock MePEG-b-PCL-b-PDMAEMA [J]. Acta Chimica Sinica, 2010, 68(23): 2449-2456.
[13]	. Synthesis and Self-assembly of Well-defined Polymer Brushes with High Grafting Density of Hydrophobic Poly(ε-caprolactone) and Hydrophilic Poly(2-(dimethylamino)ethyl methacrylate) Side Chains [J]. Acta Chimica Sinica, 2009, 67(8): 869-874.
[14]	LI Lin-Hui, TUN Jin-Dan, WANG Hong-Xia, GAO Chang-Wei. Studies of Thermoresponsive Polymer Brushes by Atomic Force Microscopy and Quartz Crystal Microbalance with Dissipation [J]. Acta Chimica Sinica, 2009, 67(24): 2867-2874.
[15]	. Studies on Atom Transfer Radical Polymerization of Phenoxyallene [J]. Acta Chimica Sinica, 2009, 67(16): 1897-1902.

含有三氟乙烯基芳基醚侧基的聚丙烯酸酯的合成与表征

Synthesis and Characterization of Polyacrylates Containing Trifluorovinyl Aryl Ether Side Group

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments