Phase Transition Induction and Upconversion Luminescence Enhancement of NaY0.95-x Yb0.03Er0.02F4 by In3+ Codoping

doi:10.6023/A13070794

Acta Chimica Sinica ›› 2013, Vol. 71 ›› Issue (12): 1639-1646.DOI: 10.6023/A13070794 Previous Articles Next Articles

Article

In³⁺共掺杂诱导NaY_0.95_-_xYb_0.03Er_0.02F₄相转变与上转换发光增强研究

俞瀚^a, 黄清明^a,b, 曹文兵^a, 张新奇^b, 俞建长^a

a 福州大学材料科学与工程学院福州 350108;
b 福州大学测试中心福州 350002

投稿日期:2013-07-27 发布日期:2013-10-12
通讯作者: 俞瀚 E-mail:fjfzyh@fzu.edu.cn
基金资助:
项目受福建省自然科学基金（No. 2013J05027）与福建省中青年教师教育科研项目（No. JA13050）资助.

Phase Transition Induction and Upconversion Luminescence Enhancement of NaY_0.95_-_x Yb_0.03Er_0.02F₄ by In³⁺ Codoping

Yu Han^a, Huang Qingming^a,b, Cao Wenbing^a, Zhang Xinqi^b, Yu Jianchang^a

a College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108;
b Instrumental Analysis & Measurement Center, Fuzhou University, Fuzhou 350002

Received:2013-07-27 Published:2013-10-12
Supported by:
Project supported by the Fujian Province Natural Science Fund (No. 2013J05027) and the Fujian Province Education-Science Project for Middle-aged and Young Teachers (No. JA13050)

1. Phase Transition Induction and Upconversion Luminescence Enhancement of NaY_0.95_-_x Yb_0.03Er_0.02F₄ by In³⁺ Codoping.PDF(821KB)

Abstract

In³⁺ was taken as a new dopant to codope NaYF₄ with Er³⁺ and Yb³⁺ by hydrothermal synthesis in this manuscript. How to improve phase transition of NaYF₄ from cubic to hexagonal and how to improve upconversion luminescence performance of hexagonal NaYF₄ are both important problems because hexagonal NaYF₄ is the most efficient matrix material for upconversion. Considering these two problems, we report the study of crystal structure and upconversion emission of In³⁺-codoped NaYF₄ to discover phase transition mechanism and upconversion luminescence properties changed with different In³⁺ codoping concentration. NaY_0.92Yb_0.03Er_0.02F₄ was tridoped with 0, 2, 4, 6, 8 and 10 mol% In³⁺ at 170 ℃ for 8 h in order to study phase transition of NaYF₄. The other group of samples was prepared by the same procedure except In³⁺codoping concentration was replaced as 0, 1, 2, 3, 4 and 5 mol% and the reaction proceeded at 190 ℃ for 12 h in order to obtain pure hexagonal NaYF₄for study of its upconversion luminescence. The change of morphologies and crystal structural transition caused by In³⁺ codoping was explored by XRD, Rietveld refinement, SEM and TEM analysis methods, while the upconversion luminescence was characterized by emission spectra and luminescence decay curves, for the relationship between crystal microstructure and luminescence properties to be discussed in our investigation. On the basis of these characterizations we found that with rising of the In³⁺ codoping concentration, the phase transition of NaYF₄ from cubic to hexagonal was improved. The intensity of upconversion luminescence was also found to be increased to the maximum when 3 mol% In³⁺ was codoped into hexagonal NaYF₄. The analysis and discussion discovered that the phase transition of NaYF₄ was correlated with the lattice distortion of cubic NaYF₄ improved by In³⁺ codoping. The intensity of upconversion luminescence was proved to be increased by the asymmetry of the local crystal field changed with the In³⁺ codoping concentration. This investigation may be helpful for design and synthesis of other functional materials.

Key words: upconversion, In³⁺ codoping, phase transition, luminescence, NaYF₄

Cite this article

Yu Han, Huang Qingming, Cao Wenbing, Zhang Xinqi, Yu Jianchang. Phase Transition Induction and Upconversion Luminescence Enhancement of NaY_0.95_-_x Yb_0.03Er_0.02F₄ by In³⁺ Codoping[J]. Acta Chimica Sinica, 2013, 71(12): 1639-1646.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Wang, F.; Liu, X. G. Chem. Soc. Rev. 2009, 38, 976.

[2] Heer, S.; Kompe, K.; Gudel, H. U.; Haase, M. Adv. Mater. 2004, 16, 2102.

[3] Vennerberg, D.; Lin, Z. Q. Sci. Adv. Mater. 2011, 3, 26.

[4] Chen, W. J. Nanosci. Nanotechnol. 2008, 8, 1019.

[5] Wang, M.; Mi, C. C.; Zhang, Y. X.; Liu, J. L.; Li, F.; Mao, C. B.; Xu, S. K. J. Phys. Chem. C 2009, 113, 19021.

[6] Ryu, J.; Park, H. Y.; Kim, K.; Kim, H.; Yoo, J. H.; Kang, M.; Im, K.; Grailhe, R.; Song, R. J. Phys. Chem. C 2010, 114, 21077.

[7] Nagarajan, S.; Zhang, Y. Nanotechnology 2011, 22, 395101.

[8] Chen, F.; Bu, W. B.; Zhang, S. J.; Liu, J. N.; Fan, W. P.; Zhou, L. P.; Peng, W. J.; Shi, J. L. Adv. Funct. Mater. 2013, 23, 298.

[9] Righini, G. C.; Ferrari, M. Riv. Nuovo. Cimento. 2005, 28, 1.

[10] Zhou, S. S.; Deng, K. M.; Wei, X. T.; Jiang, G. C.; Duan, C. K.; Chen, Y. H.; Yin, M. Opt. Commun. 2013, 291, 138.

[11] Vetrone, F.; Naccache, R.; Zamarron, A.; de la Fuente, A. J.; Sanz-Rodriguez, F.; Maestro, L. M.; Rodriguez, E. M.; Jaque, D.; Sole, J. G.; Capobianco, J. A. ACS Nano 2010, 4, 3254.

[12] Li, T. G.; Liu, S. W.; Zhang, H. P.; Wang, E. H.; Song, L. J.; Wang, P. J. Mater. Sci. 2011, 46, 2882.

[13] van der Ende, B. M.; Aarts, L.; Meijerink, A. Phys. Chem. Chem. Phys. 2009, 11, 11081.

[14] Wang, F.; Deng, R. R.; Wang, J.; Wang, Q. X.; Han, Y.; Zhu, H. M.; Chen, X. Y.; Liu, X. G. Nat. Mater. 2011, 10, 968.

[15] Li, Z. Q.; Li, X. D.; Liu, Q. Q.; Chen, X. H.; Sun, Z.; Liu, C.; Ye, X. J.; Huang, S. M. Nanotechnology 2012, 23, 345606.

[16] Zhang, J.; Shen, H. O.; Guo, W.; Wang, S. H.; Zhu, C. T.; Xue, F.; Hou, J. F.; Su, H. Q.; Yuan, Z. B. J. Power Sources 2013, 226, 47.

[17] Suyver, J. F.; Aebischer, A.; Biner, D.; Gerner, P.; Grimm, J.; Heer, S.; Kramer, K. W.; Reinhard, C.; Gudel, H. U. Opt. Mater. 2005, 27, 1111.

[18] Liang, X.; Wang, X.; Zhuang, J.; Peng, Q.; Li, Y. D. Adv. Funct. Mater. 2007, 17, 2757.

[19] Wang, L. Y.; Li, P.; Li, Y. D. Adv. Mater. 2007, 19, 3304.

[20] Mai, H. X.; Zhang, Y. W.; Si, R.; Yan, Z. G.; Sun, L. D.; You, L. P.; Yan, C. H. J. Am. Chem. Soc. 2006, 128, 6426.

[21] Mai, H. X.; Zhang, Y. W.; Sun, L. D.; Yan, C. H. J. Phys. Chem. C 2007, 111, 13721.

[22] Mai, H. X.; Zhang, Y. W.; Sun, L. D.; Yan, C. H. J. Phys. Chem. C 2007, 111, 13730.

[23] Li, C. X.; Quan, Z. W.; Yang, P. P.; Yang, J.; Lian, H. Z.; Lin, J. J. Mater. Chem. 2008, 18, 1353.

[24] Huang, Q. M.; Yu, H.; Zhang, X. Q.; Yu, J. C. Acta Chim. Sinica 2013, 71, 1071 (黄清明, 俞瀚, 张新奇, 俞建长, 化学学报, 2013, 71, 1071).

[25] Chen, J.; Guo, C. R.; Wang, M.; Huang, L.; Wang, L. P.; Mi, C. C.; Li, J.; Fang, X. X.; Mao, C. B.; Xu, S. K. J. Mater. Chem. 2011, 21, 2632.

[26] Wang, F.; Liu, X. G. J. Am. Chem. Soc. 2008, 130, 5642.

[27] Auzel, F. Chem. Rev. 2004, 104, 139.

[28] Chen, D. Q.; Yu, Y. L.; Huang, F.; Huang, P.; Yang, A. P.; Wang, Y. S. J. Am. Chem. Soc. 2010, 132, 9976.

[29] Huang, Q.; Yu, J.; Ma, E.; Lin, K. J. Phys. Chem. C 2010, 114, 4719.

[30] Judd, B. R. Phys. Rev. 1962, 127, 750.

[31] Ofelt, G. S. J. Chem. Phys. 1962, 37, 511.

[32] Dou, Q. Q.; Zhang, Y. Langmuir 2011, 27, 13236.

[33] Lifshitz, I. M.; Slyozov, V. V. J. Phys. Chem. Solids 1961, 19, 35.

In³⁺共掺杂诱导NaY_0.95_-_xYb_0.03Er_0.02F₄相转变与上转换发光增强研究

Phase Transition Induction and Upconversion Luminescence Enhancement of NaY_0.95_-_x Yb_0.03Er_0.02F₄ by In³⁺ Codoping

PDF

Supporting Info.

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Yuqing Shi, Mingzhu Chu, Bo Han, Haojie Ma, Ran Li, Xueyan Hou, Yuqi Zhang, Ji-Jiang Wang. Smart Two-dimensional Photonic Crystal Hydrogel for Accurate Detection of Hg²⁺ [J]. Acta Chimica Sinica, 2024, 82(1): 9-15.
[2]	Peng Tao, Xiaokang Zheng, Guoliang Wang, Xinghao Sheng, He Jiang, Wentao Li, Jibiao Jin, Sui-Hung Wong, Yanqin Miao, Hua Wang, Wai-Yeung Wong. Novel Bipolar Orange Emissive Iridium(III) Complexes: Design, Synthesis, and Electroluminescence^★ [J]. Acta Chimica Sinica, 2023, 81(8): 891-897.
[3]	Huimin Chen, Long Wang, Pan Zhang, Xilin Bai, Guojun Zhou. Investigation on Photoluminescence and Mechanoluminescence of Single Tb^3＋-doped Intense Green Phosphor [J]. Acta Chimica Sinica, 2023, 81(7): 771-776.
[4]	Yinfeng Wang, Meng Li, Chuanfeng Chen. Chiral Triptycene-Based Red Thermally Activated Delayed Fluorescence Polymers and Their Organic Light-Emitting Diodes^★ [J]. Acta Chimica Sinica, 2023, 81(6): 588-594.
[5]	Chen Jian, Cai Zhuoer, Jiao Shulin, Zhang Xiang, Hu Jinzhong, Liu Min, Sun Baiwang, Hua Xiuni. A Thermally Responsive Dielectric Switchable Zero-Dimensional Organic-Inorganic Hybrid Material: (C₃H₆NH₂)₂CoCl₄ [J]. Acta Chimica Sinica, 2023, 81(5): 480-485.
[6]	Shaoqin Zhang, Meiqing Li, Zhongjun Zhou, Zexing Qu. Theoretical Study on the Multiple Resonance Thermally Activated Delayed Fluorescence Process [J]. Acta Chimica Sinica, 2023, 81(2): 124-130.
[7]	Ge-Hua Wen, Wendurina, Xiumei Chen, Xiu-Fang Ma, Guo-Guo Weng, Yi-Fan Wei, Song-Song Bao, Xiaoji Xie, Shu-Xian Hu, Li-Min Zheng. Layered Uranyl Phosphonate as A Dual-response Luminescence Thermometer^★ [J]. Acta Chimica Sinica, 2023, 81(10): 1311-1317.
[8]	Yanrong Jia, Guanlei Gao, Min Xia. Methods for Adjusting Mechanoluminescence Behaviors on Crystals of Purely Organic Small Molecules [J]. Acta Chimica Sinica, 2022, 80(9): 1309-1321.
[9]	Bin Liu, Pangkuan Chen. Synthesis and Properties of Novel Circularly Polarized Luminescence Materials Based on Binaphthol Skeleton [J]. Acta Chimica Sinica, 2022, 80(7): 929-935.
[10]	Lixuan Liu, Yang Yang, Zhixiang Wei. Chiral Organic Optoelectronic Materials and Circularly Polarized Light Luminescence and Detection [J]. Acta Chimica Sinica, 2022, 80(7): 970-992.
[11]	Xufa He, Kangle Jia, Longfei Yu, Mingjie Liu, Xiaoshan Zheng, Huanling Li, Jinlan Xin, Linjia Huang. pH-Responsive Pickering Emulsions Synergistically Stabilized by Maleopimaric Acid and Alumina Nanoparticles [J]. Acta Chimica Sinica, 2022, 80(6): 765-771.
[12]	Xicheng Feng, Liangliang Zhu, Bingbing Yue. Circularly Polarized Luminescence and Dynamic Regulation Based on the co-Assembly of L/D-Lysine Hydrochloride and Photoactivated AIE Molecules [J]. Acta Chimica Sinica, 2022, 80(5): 647-651.
[13]	Ruomei Liu, Yanhui Feng, Zhuo Li, Shan Lu, Tianyong Guan, Xingjun Li, Yan Liu, Zhuo Chen, Xueyuan Chen. A Novel Near-infrared Responsive Lanthanide Upconversion Nanoplatform for Drug Delivery Based on Photocleavage of Cypate^※ [J]. Acta Chimica Sinica, 2022, 80(4): 423-427.
[14]	Xiaoke Hu, Xiaoying Shang, Ping Huang, Wei Zheng, Xueyuan Chen. Polarized Upconversion Luminescence from a Single NaYF₄:Yb³⁺/Er³⁺ Microrod for Orientation Tracking^※ [J]. Acta Chimica Sinica, 2022, 80(3): 244-248.
[15]	Wentao Wang, Gaochong Zhao, Liu Yang, Yicheng Zhou, Liming Ding. Study on Multimodal Color-switching Anti-counterfeiting Based on Magnetically Responsive Photonic Crystals and Quantum Dots [J]. Acta Chimica Sinica, 2022, 80(12): 1576-1582.

In3+共掺杂诱导NaY0.95-xYb0.03Er0.02F4相转变与上转换发光增强研究