Study on the Synthesis and Electrochemical Performance of Histidine-Functionalized Graphene Quantum Dots@Silicon Composite Anode Material

doi:10.6023/A16010060

Acta Chim. Sinica ›› 2016, Vol. 74 ›› Issue (7): 620-628.DOI: 10.6023/A16010060 Previous Articles

Article

组氨酸功能化石墨烯量子点@纳米硅负极材料的制备及电化学性能研究

孔丽娟^a, 周晓燕^a, 范赛英^a, 李在均^a,b, 顾志国^a

a. 江南大学化学与材料工程学院无锡 214122;
b. 食品胶体与生物技术教育部重点实验室无锡 214122

投稿日期:2016-01-27 发布日期:2016-07-19
通讯作者: 李在均 E-mail:zaijunli@jiangnan.edu.cn
基金资助:
项目受国家自然科学基金（No.21576115）资助.

Study on the Synthesis and Electrochemical Performance of Histidine-Functionalized Graphene Quantum Dots@Silicon Composite Anode Material

Kong Lijuan^a, Zhou Xiaoyan^a, Fan Saiying^a, Li Zaijun^a,b, Gu Zhiguo^a

a. School of Chemical and Materials Engineering, Jiangnan University, Jiangsu, Wuxi 214122;
b. Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, Wuxi 214122

Received:2016-01-27 Published:2016-07-19
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21576115).

The mixture of citric acid and histidine was used as the carbon source for the preparation of histidine- functionalized graphene quantum dots via a high temperature pyrolysis (CH-GQD). The as-prepared CH-GQD is composed of graphene sheets with an average size of 3.5 nm. The edge of graphene sheets contains the rich of hydrophilic groups. The product is very soluble in water and displays strong and stable fluorescence emission. CH-GQD was coated on the surface of silica nanoparticles to obtain graphene quantum dots-silicon composite. Then, the lithium ion battery was assembled and its electrochemical performance was investigated, in which the composite electrode and metal lithium plate were used as the anode and the cathode, respectively. The results show that the introduction of CH-GQD leads to decrease of the electron transfer impedance of the silicon cathode by more than 14.7 times, increase of the lithium ion diffusion coefficient between the electrode and the electrolyte by 310 times, and reduce of storage lithium capacity fading caused by the side reactions of the silicon atoms with the electrolyte molecules. The first discharge capacity of CH-GQD@Si cell reaches 3325 mAh·g^-1 at the current density of 50 mA·g^-1 and 1119 mAh·g^-1 at the current density of 1000 mA·g^-1. The discharge capacity can remain 1454.4 mAh·g^-1 at least after 100 cycles at the current density of 100 mA·g^-1. The battery performance of CH-GQD@Si composite electrode is obviously better than that of pristine silicon anode and the modified silicon anode with the graphene quantum dots (CA-GQD), which was produced by the pyrolysis of citric acid and alanine. Because the difference in the structure between CH-GQD and CA-GQD only is the imidazole groups on the edge of their graphene sheets, the above result also proves that the imidazole group plays important roles to improve the electrochemical performance of the composite electrode.

Key words: lithium ion batteries, silicon anode, graphene quantum dots, nanocomposite, electrochemical performance

Cite this article

Kong Lijuan, Zhou Xiaoyan, Fan Saiying, Li Zaijun, Gu Zhiguo. Study on the Synthesis and Electrochemical Performance of Histidine-Functionalized Graphene Quantum Dots@Silicon Composite Anode Material[J]. Acta Chim. Sinica, 2016, 74(7): 620-628.

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[1] Bruce, P. G.; Freunberger, S. A.; Hardwick, L. J.; Tarascon, J. M. Nature. Mater. 2012, 11, 19.
[2] Tarascon, J. M.; Armand, M. Nature 2001, 414, 359.
[3] Megahed, S.; Scrosati, B. J. Power Sources 1994, 51, 79.
[4] Kasavajjula, U.; Wang, C.; Appleby, A. J. J. Power Sources 2007, 163, 1003.
[5] Luo, F.; Zheng, J.-Y.; Chu, G.; Liu, B.-N.; Zhang, S.-L.; Li, H.; Chen, L.-Q. Acta Chim. Sinica 2015, 73, 808 (in Chinese). (罗飞, 郑杰允, 褚赓, 刘柏男, 张素林, 李泓, 陈立泉, 化学学报, 2015, 73, 808.)
[6] Ye, Y.; Zhu, J.-Y.; Yao, Y.-N.; Wang, Y.-G.; Wu, P.; Tang, Y.-W.; Zhou, Y.-M.; Lu, T.-H. Acta Chim. Sinica 2015, 73, 151 (in Chinese). (叶亚, 朱婧怡, 姚依男, 王雨果, 吴平, 唐亚文, 周益明, 陆天虹, 化学学报, 2015, 73, 151.)
[7] Wen, L.; Liu, C.-M.; Song, R.-S.; Luo, H.-Z.; Shi, Y.; Li, F.; Cheng, H.-M. Acta Chim. Sinica 2014, 72, 333 (in Chinese). (闻雷, 刘成名, 宋仁升, 罗洪泽, 石颖, 李峰, 成会明, 化学学报, 2014, 72, 333.)
[8] Boukamp, B. A.; Lesh, G. C.; Huggins, R. A. J. Electrochem. Soc. 1981, 128, 725.
[9] Obrovac, M. N.; Christensen, L. Electrochem. Solid. ST. 2004, 7, A93.
[10] Chan, C. K.; Ruffo, R.; Hong, S. S.; Huggins, R. A.; Cui, Y. J. Power Sources 2009, 189, 34.
[11] Li, H.; Huang, X. J.; Chen, L. Q.; Zhou, G. W.; Zhang, Z.; Yu, D. P.; Mo, Y. J.; Pei, N. Solid State Ionics 2000, 135, 181.
[12] Yu, Y.; Gu, L.; Zhu, C. B.; Tsukimoto, S.; Aken, P. A.; Maier, J. Adv. Mater. 2010, 22, 2247.
[13] Howe, J. Y.; Burton, D. J.; Qi, Y.; Meyer, H. M.; Nazri, M.; Nazri, G. A.; Palmer, A. C.; Lake, P. D. J. Power Sources 2013, 221, 455.
[14] Sandu, I.; Moreau, P.; Guyomard, D.; Brousse, T.; Roue, L. Solid. State Ionics 2007, 178, 1297.
[15] Ge, M.; Rong, J. P.; Fang, X.; Zhou, C. W. Nano Lett. 2012, 12, 2318.
[16] Abel, P. R.; Lin, Y. M.; Celio, H.; Heller, A.; Mullins, C. B. ACS Nano 2012, 6, 2506.
[17] Chen, D. Y.; Mei, X.; Ji, G.; Lu, M. H.; Xie, J. P.; Lu, J. M.; Lee, J. Y. Angew. Chem. Int. Ed. 2012, 51, 2409.
[18] Li, H.; Huang, X. J.; Chen, L. Q.; Wu, Z. G.; Liang, Y. Electrochem. Solid-State Lett. 1999, 11, 547.
[19] Kim, T. H.; Park, J. S.; Chang, S. K.; Choi, S.; Ryu, J. H.; Song, H. K. Adv. Eng. Mater. 2012, 2, 860.
[20] Wang, M. S.; Song, W. L.; Fan, L. Z. ChemElectroChem. 2015, 2, 1699.
[21] Wang, B.-F.; Yang, J.; Xie, J.-Y.; Wang, K.; Weng, Z.-S.; Yu, X.-G. Acta Chim. Sinica 2003, 61, 1572 (in Chinese). (王保峰, 杨军, 解晶莹, 王可, 文钟晟, 喻献国, 化学学报, 2003, 61, 1572.)
[22] Wang, B.; Li, X. L.; Zhang, X. F.; Luo, B.; Jin, M. H.; Liang, M. H.; Dayeh, S. A.; Picraux, S. T.; Zhi, L. J. ACS Nano 2013, 7, 1437.
[23] Yan, M. Y.; Wang, F. C.; Han, C. H.; Ma, X. Y.; Xu, X.; An, Q. Y.; Xu, L.; Niu, C. J.; Zhao, Y. L.; Tian, X. C.; Hu, P.; Wu, H. G.; Mai, L. Q. J. Am. Chem. Soc. 2013, 135, 18176.
[24] Luo, Z. P.; Xiao, Q. Z.; Lei, G. T.; Li, Z. H.; Tang, C. J. Carbon 2016, 98, 373.
[25] Zhao, K. N.; Zhang, L.; Xia, R.; Dong, Y. F.; Xu, W. W.; Niu, C. J.; He, L.; Yan, M. Y.; Qu, L. B.; Mai, L. Q. Small 2015, 12, 588.
[26] Chou, S. L.; Wang, J. Z.; Choucair, M.; Liu, H. K.; Stride, J. A.; Dou, S. X. Electrochem. Commun. 2010, 12, 303.
[27] Wang, J. Z.; Zhong, C.; Chou, S. L.; Liu, H. K. Electrochem. Commun. 2010, 12, 1467.
[28] Bacon, M.; Bradley, S. J.; Nann, T. Part. Part. Syst. Char. 2014, 31, 415.
[29] Huynh, W. U.; Dittmer, J. J.; Alivisatos, A. P. Science 2002, 295, 2425.
[30] Son, D. I.; Kwon, B. W.; Park, D. H.; Seo, W. S.; Yi, Y.; Angadi, B.; Lee, C. L.; Choi, W. K. Nat. Nanotechnol. 2012, 7, 465.
[31] Lin, J.; Zhang, C. G.; Yan, Z.; Zhu, Y.; Peng, Z. W.; Hauge, R. H.; Natelson, D.; Tour, J. M. Nano. Lett. 2012, 13, 72.
[32] Gao, P.; Ding, K.; Wang, Y.; Ruan, K. Q.; Diao, S. L.; Zhang, Q.; Sun, B. Q.; Jie, J. S. J. Phys. Chem. C 2014, 118, 5164.
[33] Li, R. Y.; Jiang, Y. Y.; Zhou, X. Y.; Li, Z. J.; Gu, Z. G.; Wang, G. L. Electrochim. Acta 2015, 178, 303.
[34] Tetsuka, H.; Asahi, R.; Nagoya, A.; Okamoto, K.; Tajima, I.; Ohta, R.; Okamoto, A. Adv. Mater. 2012, 24, 5333.
[35] Peng, J.; Gao, W.; Gupta, B. K.; Liu, Z.; Aburto, R. R.; Ge, L. H.; Song, L.; Alemany, L. B.; Zhan, X. B.; Gao, G. H.; Vithayathil, S. A.; Kaipparettu, B. A.; Marti, A. A.; Hayashi, T.; Zhu, J. J.; Ajayan, P. M. Nano Lett. 2012, 12, 844.
[36] Jeong, J. H.; Kim, K. H.; Jung, D. W.; Kim, K.; Lee, S. M.; Oh, E. S. J. Power Sources 2015, 300, 182.

组氨酸功能化石墨烯量子点@纳米硅负极材料的制备及电化学性能研究

Study on the Synthesis and Electrochemical Performance of Histidine-Functionalized Graphene Quantum Dots@Silicon Composite Anode Material

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