Design, Synthesis and Applications of Chiral Metal-Organic Frameworks

doi:10.6023/A20090439

Acta Chimica Sinica ›› 2020, Vol. 78 ›› Issue (12): 1336-1348.DOI: 10.6023/A20090439 Previous Articles Next Articles

Special Issue: 纪念南开大学化学学科创建100周年

Review

手性金属-有机框架的设计、合成及应用

陈中杭, 韩宗甦, 师唯, 程鹏

南开大学化学学院天津 300071

投稿日期:2020-09-23 发布日期:2020-11-10
通讯作者: 师唯 E-mail:shiwei@nankai.edu.cn
作者简介:陈中杭,博士研究生.2019年毕业于桂林理工大学(化学工程与技术专业),获工学硕士学位.2020年起在南开大学化学学院攻读博士学位.目前主要研究方向为手性金属-有机框架的构筑及其在荧光传感等领域中的应用.
韩宗甦,博士研究生.2016年毕业于南开大学,获理学学士学位.2016年起在南开大学化学学院攻读博士学位.目前主要研究方向为多功能金属-有机框架的构筑及其在手性荧光识别、气体吸附分离等领域中的应用.
师唯,南开大学化学学院教授,博士生导师,入选教育部新世纪优秀人才支持计划,国家自然科学基金优秀青年科学基金获得者.主要从事配位化学相关的研究工作.
程鹏,南开大学化学学院教授,博士生导师,教育部"长江学者"计划特聘教授,国家自然科学基金杰出青年科学基金获得者.主要从事配位化学的相关研究工作.
基金资助:
项目受国家自然科学基金（No.21861130354）、天津市自然科学基金（No.18JCJQJC47200）和中央高校基本科研业务费（Nos.63201016，63201043）资助.

Design, Synthesis and Applications of Chiral Metal-Organic Frameworks

Chen Zhonghang, Han Zongsu, Shi Wei, Cheng Peng

College of Chemistry, Nankai University, Tianjin 300071, China

Received:2020-09-23 Published:2020-11-10
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21861130354), the Natural Science Foundation of Tianjin (No. 18JCJQJC47200) and the Fundamental Research Funds for the Central Universities, Nankai University (Nos. 63201016, 63201043).

Chiral metal-organic frameworks have shown important applications in the identification and separation of enantiomers and asymmetric heterogeneous catalysis, owing to their structural diversities and multifunctionalities. Recently, the applications of chiral metal-organic frameworks have been expanded to other research fields, such as circularly polarized luminescence and chiral ferroelectrics. Compared with achiral metal-organic frameworks, it is highly challenging to synthesize chiral metal-organic frameworks, because the chirality introduction usually results in the difficulty of the crystallization and purification process for the design of chiral metal-organic frameworks. In this review, we discussed three main strategies that have been utilized to construct chiral metal-organic frameworks, including direct synthesis by chiral ligands, spontaneous resolution with achiral ligands or in the presence of chiral-template, and post-synthetic modification of achiral metal-organic frameworks. Moreover, the recent research progresses of chiral metal-organic frameworks in chiral molecular recognition, enantiomer separation, asymmetric catalysis, circularly polarized luminescence, and chiral ferroelectrics are discussed.

Key words: chirality, metal-organic frameworks, design and synthesis, property

Cite this article

Chen Zhonghang, Han Zongsu, Shi Wei, Cheng Peng. Design, Synthesis and Applications of Chiral Metal-Organic Frameworks[J]. Acta Chimica Sinica, 2020, 78(12): 1336-1348.

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手性金属-有机框架的设计、合成及应用

Design, Synthesis and Applications of Chiral Metal-Organic Frameworks

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