Progress of Application of Ring-Opening Metathesis Polymerization (ROMP) in the Synthesis of Star Polymers

doi:10.6023/A21100479

Acta Chimica Sinica ›› 2022, Vol. 80 ›› Issue (2): 229-236.DOI: 10.6023/A21100479 Previous Articles

Review

开环易位聚合(ROMP)在星型聚合物合成中的应用进展

周楚璐^a^,^b^,^c, 侯翠苹^b, 陈伟^a, 王立杰^a, 程建华^b^,^c^,^*()

a 中国电建集团中南勘测设计研究院有限公司长沙 410014
b 中国科学院长春应用化学研究所高分子物理与化学国家重点实验室长春 130022
c 中国科学技术大学合肥 230026

投稿日期:2021-10-26 发布日期:2021-12-21
通讯作者: 程建华

作者简介:

周楚璐, 中国电建集团中南勘测设计研究院有限公司博士后. 2015年本科毕业于湘潭大学. 2020年在中国科学院长春应用化学研究所(系中国科学技术大学应用化学与工程学院)获得博士学位. 主要从事新型过渡金属烯烃催化剂的设计与合成, 以及星形钌烯烃复分解催化剂的合成与应用.

侯翠苹, 中国科学院长春应用化学研究所博士研究生. 2015年本科毕业于中国矿业大学. 2021年在中国科学院长春应用化学研究所(系中国科学技术大学应用化学与工程学院)获得博士学位. 研究方向为非线性聚合物的拓扑结构设计与可控合成.

程建华, 中国科学院长春应用化学研究所研究员. 1997年本科毕业于吉林大学南岭校区(原吉林工业大学). 2003年毕业于中国科学院长春应用化学研究所, 获博士学位. 2003年至2013年在加拿大阿尔伯塔大学化学系、日本理化学研究所从事博士后研究和特别研究员. 2013年3月入职中国科学院长春应用化学研究所. 主要从事金属有机化学研究, 包括: 碱土金属、f-区金属配合物的合成以及反应性的研究、新型过渡金属烯烃催化剂的设计与合成、以及通过“先核后臂”的方法合成多嵌段、星形多臂等拓扑结构可控的功能化聚合物材料.

基金资助:
国家自然科学基金(21971232)

Progress of Application of Ring-Opening Metathesis Polymerization (ROMP) in the Synthesis of Star Polymers

Chulu Zhou^a^,^b^,^c, Cuiping Hou^b, Wei Chen^a, Lijie Wang^a, Jianhua Cheng^b^,^c()

a Power China Zhongnan Engineering Corporation Limited, Changsha 410014, China
b State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
c University of Science and Technology of China, Hefei 230026, China

Received:2021-10-26 Published:2021-12-21
Contact: Jianhua Cheng
Supported by:
National Natural Science Foundation of China(21971232)

Ring-opening metathesis polymerization (ROMP) is a strategy in which monocyclic or polycyclic olefins undergo ring-opening polymerization to form functionalized polymers. ROMP has been recognized as a powerful synthetic strategy for the synthesis of advanced polymeric materials. Recently, star polymers are receiving intense interests in materials science and nanotechnology in both academic and industrial fields due to the unique structure and property. In this review, the applications of ROMP in the synthesis of star polymers are discussed in terms of methods of polymerization, monomers, initiators and crosslinking agents. Moreover, the application fields and prospects of the ROMP synthesized star polymers, and the advantages and limitations of various ROMP methods are also presented. This work aims to promote development of ROMP in the synthesis of star-shaped polymers, provide a new scientific research approach for the synthesis of functionally complicated star-shaped polymers, and contribute to the acceleration of the commercialization of star-shaped polymer materials.

Key words: ring-opening metathesis polymerization (ROMP), star polymer, multifunctional initiator, arm-first, core-first, tandem ROMP

Cite this article

Chulu Zhou, Cuiping Hou, Wei Chen, Lijie Wang, Jianhua Cheng. Progress of Application of Ring-Opening Metathesis Polymerization (ROMP) in the Synthesis of Star Polymers[J]. Acta Chimica Sinica, 2022, 80(2): 229-236.

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Fig. & Tab. 14

Figure 1. Multifunctional norbornene crosslinking agents

Figure 2. Synthesis of star-shaped ROMP polymers by sequential addition of norbornene and cross-linker in the presence of molybdenum- alkylidene catalyst

Figure 3. Star polymers with degradable oligo(macromonomer) arms and a core crosslinked by macromolecular ladders, which give soluble microporous microgels after degradation of arms

Figure 4. One-pot preparation of an aggregation-induced emission star polymer with pH, CO2 and metal ion responsive fluorescence

Figure 5. Synthesis of poly(ethylene glycol) brush-arm star polymers via graft-through ring-opening metathesis polymerization of macromonomer 2 initiated by 1, followed by arm-first cross-linking with 3. The nitrobenzyloxycarbonyl cores of these BASPs degrade under ultraviolet light

Figure 6. The synthesis of BASPs (brush-arm star polymers) by cross-linking short (DP?=?7) PEG-based bottlebrush (co)polymers with AcXL. The acetal core (gray) can undergo degradation reactions in an acidic environment

Figure 7. The dendritic norbornene macromonomer is initiated by the trifunctional Blechert’s catalyst to prepare a three-arm star polymer through core-first strategy

Figure 8. One-shot synthesis of star gradient copolymers with controllable graft density

Figure 9. (a) Chemical structures and corresponding cartoon representations of γ-CD-Nb8, Nb-HEG and Nb-PEG. (b) Core-first/graft-from synthetic strategy for DBASCs (CD-(HEGm-PEGn)8)

Figure 10. Reaction scheme for the synthesis of tetraallyl-functionalized complex monomers {[Zn2(L)4Ln(OAc)2](NO3)} and their PNBE supported metallopolymers poly({[Zn2(L)4Ln(OAc)2](NO3)}-co-NBE)

Figure 11. Low polymerization degree ROMP brush polymer reacts with alkyne-terminated polymer, followed by self-assembly, and forms an asymmetric miktoarm star polymers

Figure 12. Synthesis of thermoresponsive optically active star block copolymer

Figure 13. Preparation of three-arm star polymers employing the Cu-catalyzed 1,3-dipolar cycloaddition of azide end-functionalized ROM polymers (PNEONI-N3)

Figure 14. Synthetic routes to ABC miktoarm star terpolyphosphoesters via sequential combination of ROMP, ROP and ADMET polymerization

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开环易位聚合(ROMP)在星型聚合物合成中的应用进展

Progress of Application of Ring-Opening Metathesis Polymerization (ROMP) in the Synthesis of Star Polymers

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